Fabrication of Pt-Pd@ITO grown heterogeneous nanocatalyst as efficient remediator for toxic methyl parathion in aqueous media
In this study, nano-sized ITO supported Pt-Pd bimetallic catalyst was synthesized for the degradation of methyl parathion pesticide, a common extremely toxic contaminant in aqueous solution. On the characterization with different techniques, a beautiful scenario of honeycomb architecture composed of...
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| Veröffentlicht in: | Environmental science and pollution research international 2020-03, Vol.27 (9), p.9970-9978 |
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| container_title | Environmental science and pollution research international |
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| creator | Mahar, Ali Muhammad Balouch, Aamna Talpur, Farah Naz Abdullah Panah, Pirah Kumar, Raj Kumar, Ameet Pato, Abdul Hameed Mal, Dadu Kumar, Sagar Umar, Akrajas Ali |
| description | In this study, nano-sized ITO supported Pt-Pd bimetallic catalyst was synthesized for the degradation of methyl parathion pesticide, a common extremely toxic contaminant in aqueous solution. On the characterization with different techniques, a beautiful scenario of honeycomb architecture composed of ultra-small nanoneedles or fine hairs was found. Average size of nanocatalyst also confirmed which was in the range of 3–5 nm. High percent degradation (94%) was obtained in 30 s using 1.5 × 10
− 1
mg of synthesized nanocatalyst, 0.5 mM NaBH
4
, and 110 W microwave radiations power. Recyclability of nanocatalyst was efficient till 4th cycle observed during study of reusability. The supported Pt-Pd bimetallic nanocatalyst on ITO displayed many advantages over conventional methods for degradation of methyl parathion pesticide, such as high percent degradation, short reaction time, small amount of nanocatalyst, and multitime reusability.
Graphical abstract
Schematic illustration of reaction for degradation of methyl parathion |
| doi_str_mv | 10.1007/s11356-019-07548-y |
| format | Article |
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− 1
mg of synthesized nanocatalyst, 0.5 mM NaBH
4
, and 110 W microwave radiations power. Recyclability of nanocatalyst was efficient till 4th cycle observed during study of reusability. The supported Pt-Pd bimetallic nanocatalyst on ITO displayed many advantages over conventional methods for degradation of methyl parathion pesticide, such as high percent degradation, short reaction time, small amount of nanocatalyst, and multitime reusability.
Graphical abstract
Schematic illustration of reaction for degradation of methyl parathion</description><identifier>ISSN: 0944-1344</identifier><identifier>EISSN: 1614-7499</identifier><identifier>DOI: 10.1007/s11356-019-07548-y</identifier><identifier>PMID: 31933082</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Acids ; Aquatic Pollution ; Aqueous solutions ; architecture ; Atmospheric Protection/Air Quality Control/Air Pollution ; Bimetals ; Catalysis ; Catalysts ; Chemical synthesis ; Chemicals ; Contaminants ; Degradation ; Earth and Environmental Science ; Ecotoxicology ; Environment ; Environmental Chemistry ; Environmental Health ; Environmental impact ; Environmental science ; Fabrication ; Indium tin oxides ; Insecticides ; Methyl Parathion ; Nanocatalysis ; nanocatalysts ; Nanoparticles ; Nervous system ; Palladium ; Parathion ; parathion-methyl ; Pesticide toxicity ; Pesticides ; Pesticides - analysis ; Platinum ; Potassium ; Reaction time ; Recyclability ; Research Article ; toxicity ; Waste Water Technology ; Water ; Water Management ; Water Pollution Control</subject><ispartof>Environmental science and pollution research international, 2020-03, Vol.27 (9), p.9970-9978</ispartof><rights>Springer-Verlag GmbH Germany, part of Springer Nature 2020</rights><rights>Environmental Science and Pollution Research is a copyright of Springer, (2020). All Rights Reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c445t-3e55e39b4c5ceb6dac2e4ae91026e9cda23ea9de518988dbee765e423e727df03</citedby><cites>FETCH-LOGICAL-c445t-3e55e39b4c5ceb6dac2e4ae91026e9cda23ea9de518988dbee765e423e727df03</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11356-019-07548-y$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11356-019-07548-y$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27903,27904,41467,42536,51297</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/31933082$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Mahar, Ali Muhammad</creatorcontrib><creatorcontrib>Balouch, Aamna</creatorcontrib><creatorcontrib>Talpur, Farah Naz</creatorcontrib><creatorcontrib>Abdullah</creatorcontrib><creatorcontrib>Panah, Pirah</creatorcontrib><creatorcontrib>Kumar, Raj</creatorcontrib><creatorcontrib>Kumar, Ameet</creatorcontrib><creatorcontrib>Pato, Abdul Hameed</creatorcontrib><creatorcontrib>Mal, Dadu</creatorcontrib><creatorcontrib>Kumar, Sagar</creatorcontrib><creatorcontrib>Umar, Akrajas Ali</creatorcontrib><title>Fabrication of Pt-Pd@ITO grown heterogeneous nanocatalyst as efficient remediator for toxic methyl parathion in aqueous media</title><title>Environmental science and pollution research international</title><addtitle>Environ Sci Pollut Res</addtitle><addtitle>Environ Sci Pollut Res Int</addtitle><description>In this study, nano-sized ITO supported Pt-Pd bimetallic catalyst was synthesized for the degradation of methyl parathion pesticide, a common extremely toxic contaminant in aqueous solution. On the characterization with different techniques, a beautiful scenario of honeycomb architecture composed of ultra-small nanoneedles or fine hairs was found. Average size of nanocatalyst also confirmed which was in the range of 3–5 nm. High percent degradation (94%) was obtained in 30 s using 1.5 × 10
− 1
mg of synthesized nanocatalyst, 0.5 mM NaBH
4
, and 110 W microwave radiations power. Recyclability of nanocatalyst was efficient till 4th cycle observed during study of reusability. The supported Pt-Pd bimetallic nanocatalyst on ITO displayed many advantages over conventional methods for degradation of methyl parathion pesticide, such as high percent degradation, short reaction time, small amount of nanocatalyst, and multitime reusability.
Graphical abstract
Schematic illustration of reaction for degradation of methyl parathion</description><subject>Acids</subject><subject>Aquatic Pollution</subject><subject>Aqueous solutions</subject><subject>architecture</subject><subject>Atmospheric Protection/Air Quality Control/Air Pollution</subject><subject>Bimetals</subject><subject>Catalysis</subject><subject>Catalysts</subject><subject>Chemical synthesis</subject><subject>Chemicals</subject><subject>Contaminants</subject><subject>Degradation</subject><subject>Earth and Environmental Science</subject><subject>Ecotoxicology</subject><subject>Environment</subject><subject>Environmental Chemistry</subject><subject>Environmental Health</subject><subject>Environmental impact</subject><subject>Environmental science</subject><subject>Fabrication</subject><subject>Indium tin oxides</subject><subject>Insecticides</subject><subject>Methyl Parathion</subject><subject>Nanocatalysis</subject><subject>nanocatalysts</subject><subject>Nanoparticles</subject><subject>Nervous system</subject><subject>Palladium</subject><subject>Parathion</subject><subject>parathion-methyl</subject><subject>Pesticide toxicity</subject><subject>Pesticides</subject><subject>Pesticides - analysis</subject><subject>Platinum</subject><subject>Potassium</subject><subject>Reaction time</subject><subject>Recyclability</subject><subject>Research Article</subject><subject>toxicity</subject><subject>Waste Water Technology</subject><subject>Water</subject><subject>Water Management</subject><subject>Water Pollution Control</subject><issn>0944-1344</issn><issn>1614-7499</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><sourceid>GNUQQ</sourceid><recordid>eNp9kT9PHDEQxS2UKFxIvgAFspQmjRP_3V13IBQIEhIUpLa83tk7oz37sH0iW-S7Y-4gSClSjCyNf_PejB5Cx4x-Y5S23zNjQjWEMk1oq2RH5gO0YA2TpJVav0MLqqUkTEh5iD7mfE8pp5q3H9ChYFoI2vEF-nNh--SdLT4GHEd8W8jtcHp1d4OXKT4GvIICKS4hQNxmHGyIlbXTnAu2GcM4euchFJxgDYO3JSY81irxt3d4DWU1T3hjky2rZwMfsH3Y7qR2-Cf0frRThs8v7xH6dfHj7vwnub65vDo_uyZOSlWIAKVA6F465aBvBus4SAuaUd6AdoPlAqweQLFOd93QA7SNAlm7LW-HkYoj9HWvu0mx-udi1j47mCa7u8twKVinqOhERb_8g97HbQp1O8NFx3RDK1cpvqdcijknGM0m-bVNs2HUPIdj9uGYGo7ZhWPmOnTyIr3t6_l_R17TqIDYA7l-hSWkN-__yD4BuFCdLA</recordid><startdate>20200301</startdate><enddate>20200301</enddate><creator>Mahar, Ali Muhammad</creator><creator>Balouch, Aamna</creator><creator>Talpur, Farah Naz</creator><creator>Abdullah</creator><creator>Panah, Pirah</creator><creator>Kumar, Raj</creator><creator>Kumar, Ameet</creator><creator>Pato, Abdul Hameed</creator><creator>Mal, Dadu</creator><creator>Kumar, Sagar</creator><creator>Umar, Akrajas Ali</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>7QL</scope><scope>7SN</scope><scope>7T7</scope><scope>7TV</scope><scope>7U7</scope><scope>7WY</scope><scope>7WZ</scope><scope>7X7</scope><scope>7XB</scope><scope>87Z</scope><scope>88E</scope><scope>88I</scope><scope>8AO</scope><scope>8C1</scope><scope>8FD</scope><scope>8FI</scope><scope>8FJ</scope><scope>8FK</scope><scope>8FL</scope><scope>ABUWG</scope><scope>AEUYN</scope><scope>AFKRA</scope><scope>ATCPS</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BEZIV</scope><scope>BHPHI</scope><scope>C1K</scope><scope>CCPQU</scope><scope>DWQXO</scope><scope>FR3</scope><scope>FRNLG</scope><scope>FYUFA</scope><scope>F~G</scope><scope>GHDGH</scope><scope>GNUQQ</scope><scope>HCIFZ</scope><scope>K60</scope><scope>K6~</scope><scope>K9.</scope><scope>L.-</scope><scope>M0C</scope><scope>M0S</scope><scope>M1P</scope><scope>M2P</scope><scope>M7N</scope><scope>P64</scope><scope>PATMY</scope><scope>PQBIZ</scope><scope>PQBZA</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PYCSY</scope><scope>Q9U</scope><scope>7S9</scope><scope>L.6</scope></search><sort><creationdate>20200301</creationdate><title>Fabrication of Pt-Pd@ITO grown heterogeneous nanocatalyst as efficient remediator for toxic methyl parathion in aqueous media</title><author>Mahar, Ali Muhammad ; Balouch, Aamna ; Talpur, Farah Naz ; Abdullah ; Panah, Pirah ; Kumar, Raj ; Kumar, Ameet ; Pato, Abdul Hameed ; Mal, Dadu ; Kumar, Sagar ; Umar, Akrajas Ali</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c445t-3e55e39b4c5ceb6dac2e4ae91026e9cda23ea9de518988dbee765e423e727df03</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Acids</topic><topic>Aquatic Pollution</topic><topic>Aqueous solutions</topic><topic>architecture</topic><topic>Atmospheric Protection/Air Quality Control/Air Pollution</topic><topic>Bimetals</topic><topic>Catalysis</topic><topic>Catalysts</topic><topic>Chemical synthesis</topic><topic>Chemicals</topic><topic>Contaminants</topic><topic>Degradation</topic><topic>Earth and Environmental Science</topic><topic>Ecotoxicology</topic><topic>Environment</topic><topic>Environmental Chemistry</topic><topic>Environmental Health</topic><topic>Environmental impact</topic><topic>Environmental science</topic><topic>Fabrication</topic><topic>Indium tin oxides</topic><topic>Insecticides</topic><topic>Methyl Parathion</topic><topic>Nanocatalysis</topic><topic>nanocatalysts</topic><topic>Nanoparticles</topic><topic>Nervous system</topic><topic>Palladium</topic><topic>Parathion</topic><topic>parathion-methyl</topic><topic>Pesticide toxicity</topic><topic>Pesticides</topic><topic>Pesticides - 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Academic</collection><jtitle>Environmental science and pollution research international</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Mahar, Ali Muhammad</au><au>Balouch, Aamna</au><au>Talpur, Farah Naz</au><au>Abdullah</au><au>Panah, Pirah</au><au>Kumar, Raj</au><au>Kumar, Ameet</au><au>Pato, Abdul Hameed</au><au>Mal, Dadu</au><au>Kumar, Sagar</au><au>Umar, Akrajas Ali</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Fabrication of Pt-Pd@ITO grown heterogeneous nanocatalyst as efficient remediator for toxic methyl parathion in aqueous media</atitle><jtitle>Environmental science and pollution research international</jtitle><stitle>Environ Sci Pollut Res</stitle><addtitle>Environ Sci Pollut Res Int</addtitle><date>2020-03-01</date><risdate>2020</risdate><volume>27</volume><issue>9</issue><spage>9970</spage><epage>9978</epage><pages>9970-9978</pages><issn>0944-1344</issn><eissn>1614-7499</eissn><abstract>In this study, nano-sized ITO supported Pt-Pd bimetallic catalyst was synthesized for the degradation of methyl parathion pesticide, a common extremely toxic contaminant in aqueous solution. On the characterization with different techniques, a beautiful scenario of honeycomb architecture composed of ultra-small nanoneedles or fine hairs was found. Average size of nanocatalyst also confirmed which was in the range of 3–5 nm. High percent degradation (94%) was obtained in 30 s using 1.5 × 10
− 1
mg of synthesized nanocatalyst, 0.5 mM NaBH
4
, and 110 W microwave radiations power. Recyclability of nanocatalyst was efficient till 4th cycle observed during study of reusability. The supported Pt-Pd bimetallic nanocatalyst on ITO displayed many advantages over conventional methods for degradation of methyl parathion pesticide, such as high percent degradation, short reaction time, small amount of nanocatalyst, and multitime reusability.
Graphical abstract
Schematic illustration of reaction for degradation of methyl parathion</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><pmid>31933082</pmid><doi>10.1007/s11356-019-07548-y</doi><tpages>9</tpages></addata></record> |
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| identifier | ISSN: 0944-1344 |
| ispartof | Environmental science and pollution research international, 2020-03, Vol.27 (9), p.9970-9978 |
| issn | 0944-1344 1614-7499 |
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| source | MEDLINE; SpringerLink Journals |
| subjects | Acids Aquatic Pollution Aqueous solutions architecture Atmospheric Protection/Air Quality Control/Air Pollution Bimetals Catalysis Catalysts Chemical synthesis Chemicals Contaminants Degradation Earth and Environmental Science Ecotoxicology Environment Environmental Chemistry Environmental Health Environmental impact Environmental science Fabrication Indium tin oxides Insecticides Methyl Parathion Nanocatalysis nanocatalysts Nanoparticles Nervous system Palladium Parathion parathion-methyl Pesticide toxicity Pesticides Pesticides - analysis Platinum Potassium Reaction time Recyclability Research Article toxicity Waste Water Technology Water Water Management Water Pollution Control |
| title | Fabrication of Pt-Pd@ITO grown heterogeneous nanocatalyst as efficient remediator for toxic methyl parathion in aqueous media |
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