O‐Isocyanates as Uncharged 1,3‐Dipole Equivalents in [3+2] Cycloadditions

1,3‐Dipoles are commonly used in [3+2] cycloadditions, whereas isoelectronic uncharged dipole variants remain underdeveloped. In contrast to conventional 1,3‐dipoles, uncharged dipole equivalents form zwitterionic cycloadducts, which can be exploited to build further molecular complexity. In this wo...

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Veröffentlicht in:	Angewandte Chemie International Edition 2020-12, Vol.59 (51), p.23188-23197
Hauptverfasser:	Allen, Meredith A., Ivanovich, Ryan A., Beauchemin, André M.
Format:	Artikel
Sprache:	eng
Schlagworte:	[3+2] cycloaddition Alkenes Cycloaddition C−H amination Dipoles Equivalence Isocyanates nitrenes oxycarbonylation Reagents
Online-Zugang:	Volltext
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