The gas-phase reaction of chlorine nitrate with water vapor

The kinetics of the reaction of chlorine nitrate (ClONO2) with water vapor have been investigated in large‐volume (2500‐L and 5800‐L) Teflon or Teflon‐coated environmental chambers to assess the importance of this reaction as a loss process for odd nitrogen in the stratosphere. These data show that...

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Veröffentlicht in:	Geophysical research letters 1986-02, Vol.13 (2), p.117-120
Hauptverfasser:	Atkinson, Roger, Tuazon, Ernesto C., Mac Leod, Hélène, Aschmann, Sara M., Winer, Arthur M.
Format:	Artikel
Sprache:	eng
Schlagworte:	Atmospheric composition. Chemical and photochemical reactions Chambers Chlorine Earth, ocean, space Exact sciences and technology External geophysics Gas phases Geophysics Nitrates Physics of the high neutral atmosphere Rate constants Stratosphere Water vapor
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Zusammenfassung:	The kinetics of the reaction of chlorine nitrate (ClONO2) with water vapor have been investigated in large‐volume (2500‐L and 5800‐L) Teflon or Teflon‐coated environmental chambers to assess the importance of this reaction as a loss process for odd nitrogen in the stratosphere. These data show that the upper limit rate constant for the homogeneous gas phase reaction between ClONO2 and H2O is
ISSN:	0094-8276 1944-8007
DOI:	10.1029/GL013i002p00117