Metal catalyst-free photo-induced alkyl C-O bond borylation

Metal catalyst free, blue visible light-induced C-O bond borylation of unactivated tertiary alkyl methyl oxalates has been developed to furnish tertiary alkyl boronates. From the secondary alcohols activated with imidazolylthionyl, moderate yields of boronates were attained under standard photo-indu...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2020-09, Vol.56 (7), p.1219-1222
Hauptverfasser: Ma, Guobin, Chen, Changzhou, Talukdar, Sangita, Zhao, Xinluo, Lei, Chuanhu, Gong, Hegui
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Sprache:eng
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