Synthesis and characterization of semiconductive poly-1,4-dimethoxybenzene and its derived polyquinone
Poly-1,4-dimethoxybenzene has been synthesized by the anodic oxidation of 1,4-dimethoxybenzene in aprotic electrolytes. The black polymer is a doped semiconductor as formed. This material is converted to polymeric (oligomeric) hydroquinone and quinone. The polymers are insoluble in all common solven...
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| Veröffentlicht in: | Journal of the Electrochemical Society 1986-04, Vol.133 (4), p.836-841 |
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| container_title | Journal of the Electrochemical Society |
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| creator | FOOS, J. S ERKER, S. M REMBETSY, L. M |
| description | Poly-1,4-dimethoxybenzene has been synthesized by the anodic oxidation of 1,4-dimethoxybenzene in aprotic electrolytes. The black polymer is a doped semiconductor as formed. This material is converted to polymeric (oligomeric) hydroquinone and quinone. The polymers are insoluble in all common solvents except for the polyhydroquinone in aqueous base. A coulombic titration of this quinone, using an electrode compounded with carbon and in an aprotic electrolyte, gave an equivalent weight corresponding to similar to 0.5e super(-) per quinone unit. Similar results were observed in the initial cycles in Li cells, however, the capacity of the electrode degraded on cycling. |
| doi_str_mv | 10.1149/1.2108689 |
| format | Article |
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Similar results were observed in the initial cycles in Li cells, however, the capacity of the electrode degraded on cycling.</description><subject>Applied sciences</subject><subject>Electrical, magnetic and optical properties</subject><subject>Exact sciences and technology</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>Properties and characterization</subject><issn>0013-4651</issn><issn>1945-7111</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1986</creationdate><recordtype>article</recordtype><recordid>eNo9kF9LwzAUR4MoOKcPfoM-iCDYmdskTfsow38w8EF9LmlywyJdsjXtsPv0dm74dLlwfufhEHINdAbAyweYZUCLvChPyARKLlIJAKdkQimwlOcCzslFjN_jCwWXE2I_Bt8tMbqYKG8SvVSt0h22bqc6F3wSbBJx5XTwpted22KyDs2Qwj1PjVthtww_Q41-hx7_BK6LiRnnWzR_5KZ3Pni8JGdWNRGvjndKvp6fPuev6eL95W3-uEg1E6xLc0FNzpjKtMplbUUmpAItQHGDaCRIlJxnBnQpshptbbnMubCK1rwGwWs2JbcH77oNmx5jV61c1Ng0ymPoY5XxrATK5AjeHUDdhhhbtNW6dSvVDhXQal-ygupYcmRvjlIVtWpsq7x28X9QFPu4JfsFxmd0RA</recordid><startdate>19860401</startdate><enddate>19860401</enddate><creator>FOOS, J. 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M</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c353t-650d633a2ca67bf5257a1c51a4deed717e7442d1c952befbf47645fa0b4b154b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1986</creationdate><topic>Applied sciences</topic><topic>Electrical, magnetic and optical properties</topic><topic>Exact sciences and technology</topic><topic>Organic polymers</topic><topic>Physicochemistry of polymers</topic><topic>Properties and characterization</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>FOOS, J. S</creatorcontrib><creatorcontrib>ERKER, S. M</creatorcontrib><creatorcontrib>REMBETSY, L. 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A coulombic titration of this quinone, using an electrode compounded with carbon and in an aprotic electrolyte, gave an equivalent weight corresponding to similar to 0.5e super(-) per quinone unit. Similar results were observed in the initial cycles in Li cells, however, the capacity of the electrode degraded on cycling.</abstract><cop>Pennington, NJ</cop><pub>Electrochemical Society</pub><doi>10.1149/1.2108689</doi><tpages>6</tpages></addata></record> |
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| ispartof | Journal of the Electrochemical Society, 1986-04, Vol.133 (4), p.836-841 |
| issn | 0013-4651 1945-7111 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_24291037 |
| source | IOP Publishing Journals |
| subjects | Applied sciences Electrical, magnetic and optical properties Exact sciences and technology Organic polymers Physicochemistry of polymers Properties and characterization |
| title | Synthesis and characterization of semiconductive poly-1,4-dimethoxybenzene and its derived polyquinone |
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