Impact initiation of hexanitrostilbene
A study has been made of the initiation of hexanitrostilbene (HNS) under impact using high-speed photography at microsecond framing rates. The photographic sequences show that upon impact the layer of explosive undergoes bulk plastic flow at speeds of over 250 m s −1. Initiation occurs after this ca...
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Veröffentlicht in: | Combustion and flame 1984-01, Vol.56 (3), p.269-277 |
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creator | Mohan, V.Krishna Field, J.E. |
description | A study has been made of the initiation of hexanitrostilbene (HNS) under impact using high-speed photography at microsecond framing rates. The photographic sequences show that upon impact the layer of explosive undergoes bulk plastic flow at speeds of over 250 m s
−1. Initiation occurs after this catastrophic failure of the explosive due to the fact that the adiabatic heating produced by plastic deformation is extremely localized in nature. From a comparison of the melting points, uniaxial yield stress values, flow properties, and the ignition characteristics for several organic secondary explosives, it appears that explosives with high strength values are more likely to exhibit both a rapid mechanical failure and resultant ignition during impact. Addition of polycarbonate (PC) has been found to sensitize the explosive. Strain-gauge measurements of impact of pure HNS and HNS/PC samples have shown that a sudden pressure drop occurs before ignition due to rapid failure of the test material, the latter being in agreement with the photographic observations. |
doi_str_mv | 10.1016/0010-2180(84)90061-0 |
format | Article |
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−1. Initiation occurs after this catastrophic failure of the explosive due to the fact that the adiabatic heating produced by plastic deformation is extremely localized in nature. From a comparison of the melting points, uniaxial yield stress values, flow properties, and the ignition characteristics for several organic secondary explosives, it appears that explosives with high strength values are more likely to exhibit both a rapid mechanical failure and resultant ignition during impact. Addition of polycarbonate (PC) has been found to sensitize the explosive. Strain-gauge measurements of impact of pure HNS and HNS/PC samples have shown that a sudden pressure drop occurs before ignition due to rapid failure of the test material, the latter being in agreement with the photographic observations.</description><identifier>ISSN: 0010-2180</identifier><identifier>EISSN: 1556-2921</identifier><identifier>DOI: 10.1016/0010-2180(84)90061-0</identifier><identifier>CODEN: CBFMAO</identifier><language>eng</language><publisher>New York, NY: Elsevier Inc</publisher><subject>Chemistry ; Combustion. Flame ; Exact sciences and technology ; General and physical chemistry</subject><ispartof>Combustion and flame, 1984-01, Vol.56 (3), p.269-277</ispartof><rights>1984</rights><rights>1985 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c364t-39ea090e318f05b604f148b059cd7f00c395ea27fa6f074d8ec198e90d4fd843</citedby><cites>FETCH-LOGICAL-c364t-39ea090e318f05b604f148b059cd7f00c395ea27fa6f074d8ec198e90d4fd843</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/0010-2180(84)90061-0$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>315,781,785,3551,27929,27930,46000</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=9122725$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Mohan, V.Krishna</creatorcontrib><creatorcontrib>Field, J.E.</creatorcontrib><title>Impact initiation of hexanitrostilbene</title><title>Combustion and flame</title><description>A study has been made of the initiation of hexanitrostilbene (HNS) under impact using high-speed photography at microsecond framing rates. The photographic sequences show that upon impact the layer of explosive undergoes bulk plastic flow at speeds of over 250 m s
−1. Initiation occurs after this catastrophic failure of the explosive due to the fact that the adiabatic heating produced by plastic deformation is extremely localized in nature. From a comparison of the melting points, uniaxial yield stress values, flow properties, and the ignition characteristics for several organic secondary explosives, it appears that explosives with high strength values are more likely to exhibit both a rapid mechanical failure and resultant ignition during impact. Addition of polycarbonate (PC) has been found to sensitize the explosive. Strain-gauge measurements of impact of pure HNS and HNS/PC samples have shown that a sudden pressure drop occurs before ignition due to rapid failure of the test material, the latter being in agreement with the photographic observations.</description><subject>Chemistry</subject><subject>Combustion. Flame</subject><subject>Exact sciences and technology</subject><subject>General and physical chemistry</subject><issn>0010-2180</issn><issn>1556-2921</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1984</creationdate><recordtype>article</recordtype><recordid>eNp9kM1LAzEQxYMoWKv_gYcepOhhdfKx2eQiSPGjUPDSe0izE4xsd2uSiv73plZ69DQw_N6b94aQSwq3FKi8A6BQMargWokbDSBpBUdkROtaVkwzekxGB-SUnKX0DgCN4HxEpvP1xro8CX3IweYw9JPBT97wy5ZFHFIO3Qp7PCcn3nYJL_7mmCyfHpezl2rx-jyfPSwqx6XIFddoQQNyqjzUKwnCU6FWUGvXNh7AcV2jZY230pcArUJHtUINrfCtEnxMpnvbTRw-tpiyWYfksOtsj8M2GSZYI5mSBRR70JWMKaI3mxjWNn4bCmb3E7MrbHaFjRLm9ycGiuzqz98mZzsfbe9COmg1ZaxhdcHu9xiWqp8Bo0kuYO-wDRFdNu0Q_r_zA6yHc44</recordid><startdate>19840101</startdate><enddate>19840101</enddate><creator>Mohan, V.Krishna</creator><creator>Field, J.E.</creator><general>Elsevier Inc</general><general>Elsevier Science</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>8FD</scope><scope>F28</scope><scope>FR3</scope><scope>H8D</scope><scope>L7M</scope></search><sort><creationdate>19840101</creationdate><title>Impact initiation of hexanitrostilbene</title><author>Mohan, V.Krishna ; Field, J.E.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c364t-39ea090e318f05b604f148b059cd7f00c395ea27fa6f074d8ec198e90d4fd843</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1984</creationdate><topic>Chemistry</topic><topic>Combustion. Flame</topic><topic>Exact sciences and technology</topic><topic>General and physical chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Mohan, V.Krishna</creatorcontrib><creatorcontrib>Field, J.E.</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Technology Research Database</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>Aerospace Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Combustion and flame</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Mohan, V.Krishna</au><au>Field, J.E.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Impact initiation of hexanitrostilbene</atitle><jtitle>Combustion and flame</jtitle><date>1984-01-01</date><risdate>1984</risdate><volume>56</volume><issue>3</issue><spage>269</spage><epage>277</epage><pages>269-277</pages><issn>0010-2180</issn><eissn>1556-2921</eissn><coden>CBFMAO</coden><abstract>A study has been made of the initiation of hexanitrostilbene (HNS) under impact using high-speed photography at microsecond framing rates. The photographic sequences show that upon impact the layer of explosive undergoes bulk plastic flow at speeds of over 250 m s
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subjects | Chemistry Combustion. Flame Exact sciences and technology General and physical chemistry |
title | Impact initiation of hexanitrostilbene |
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