Effects of Water and Different Solutes on Carbon‐Nanotube Low‐Voltage Field‐Effect Transistors

Semiconducting single‐walled carbon nanotubes (swCNTs) are a promising class of materials for emerging applications. In particular, they are demonstrated to possess excellent biosensing capabilities, and are poised to address existing challenges in sensor reliability, sensitivity, and selectivity. T...

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Veröffentlicht in:Small (Weinheim an der Bergstrasse, Germany) Germany), 2020-08, Vol.16 (34), p.e2002875-n/a
Hauptverfasser: Foudeh, Amir M., Pfattner, Raphael, Lu, Shiheng, Kubzdela, Nicola S., Gao, Theodore Z., Lei, Ting, Bao, Zhenan
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container_issue 34
container_start_page e2002875
container_title Small (Weinheim an der Bergstrasse, Germany)
container_volume 16
creator Foudeh, Amir M.
Pfattner, Raphael
Lu, Shiheng
Kubzdela, Nicola S.
Gao, Theodore Z.
Lei, Ting
Bao, Zhenan
description Semiconducting single‐walled carbon nanotubes (swCNTs) are a promising class of materials for emerging applications. In particular, they are demonstrated to possess excellent biosensing capabilities, and are poised to address existing challenges in sensor reliability, sensitivity, and selectivity. This work focuses on swCNT field‐effect transistors (FETs) employing rubbery double‐layer capacitive dielectric poly(vinylidene fluoride‐co‐hexafluoropropylene). These devices exhibit small device‐to‐device variation as well as high current output at low voltages (
doi_str_mv 10.1002/smll.202002875
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In particular, they are demonstrated to possess excellent biosensing capabilities, and are poised to address existing challenges in sensor reliability, sensitivity, and selectivity. This work focuses on swCNT field‐effect transistors (FETs) employing rubbery double‐layer capacitive dielectric poly(vinylidene fluoride‐co‐hexafluoropropylene). These devices exhibit small device‐to‐device variation as well as high current output at low voltages (&lt;0.5 V), making them compatible with most physiological liquids. Using this platform, the swCNT devices are directly exposed to aqueous solutions containing different solutes to characterize their effects on FET current–voltage (FET I–V) characteristics. Clear deviation from ideal characteristics is observed when swCNTs are directly contacted by water. Such changes are attributed to strong interactions between water molecules and sp2‐hybridized carbon structures. Selective response to Hg2+ is discussed along with reversible pH effect using two distinct device geometries. Additionally, the influence of aqueous ammonium/ammonia in direct contact with the swCNTs is investigated. Understanding the FET I–V characteristics of low‐voltage swCNT FETs may provide insights for future development of stable, reliable, and selective biosensor systems. Low voltage carbon nanotube field‐effect transistors employing a rubbery double‐layer dielectric allow exposing devices to aqueous solutions and study effects on current–voltage characteristics. Selective response to Hg2+ is discussed along with reversible pH effect and compared with ammonium/ammonia in direct contact with the carbon nanotube network. 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Selective response to Hg2+ is discussed along with reversible pH effect using two distinct device geometries. Additionally, the influence of aqueous ammonium/ammonia in direct contact with the swCNTs is investigated. Understanding the FET I–V characteristics of low‐voltage swCNT FETs may provide insights for future development of stable, reliable, and selective biosensor systems. Low voltage carbon nanotube field‐effect transistors employing a rubbery double‐layer dielectric allow exposing devices to aqueous solutions and study effects on current–voltage characteristics. Selective response to Hg2+ is discussed along with reversible pH effect and compared with ammonium/ammonia in direct contact with the carbon nanotube network. 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source Wiley-Blackwell Journals
subjects Ammonia
Aqueous solutions
Biosensors
Carbon
Electric potential
Field effect transistors
low‐voltage field‐effect transistors
Mercury (metal)
Nanotechnology
response mechanisms
Selectivity
Semiconductor devices
Single wall carbon nanotubes
single‐walled carbon nanotubes
Transistors
Vinylidene
Vinylidene fluoride
Voltage
water and electrolyte solutions
Water chemistry
title Effects of Water and Different Solutes on Carbon‐Nanotube Low‐Voltage Field‐Effect Transistors
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