Highly Enantioselective Iridium-Catalyzed Coupling Reaction of Vinyl Azides and Racemic Allylic Carbonates

The iridium-catalyzed enantioselective coupling reaction of vinyl azides and allylic electrophiles is presented and provides access to β-chiral carbonyl derivatives. Vinyl azides are used as acetamide enolate or acetonitrile carbanion surrogates, leading to γ,δ-unsaturated β-substituted amides as we...

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Veröffentlicht in:	Journal of the American Chemical Society 2020-08, Vol.142 (31), p.13398-13405
Hauptverfasser:	Han, Min, Yang, Min, Wu, Rui, Li, Yang, Jia, Tao, Gao, Yuanji, Ni, Hai-Liang, Hu, Ping, Wang, Bi-Qin, Cao, Peng
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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