Highly Electrocatalytic Ethylene Production from CO2 on Nanodefective Cu Nanosheets
The electrochemical synthesis of chemicals from carbon dioxide, which is an easily available and renewable carbon resource, is of great importance. However, to achieve high product selectivity for desirable C2 products like ethylene is a big challenge. Here we design Cu nanosheets with nanoscaled de...
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| Veröffentlicht in: | Journal of the American Chemical Society 2020-08, Vol.142 (31), p.13606-13613 |
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| container_issue | 31 |
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| container_title | Journal of the American Chemical Society |
| container_volume | 142 |
| creator | Zhang, Bingxing Zhang, Jianling Hua, Manli Wan, Qiang Su, Zhuizhui Tan, Xiuniang Liu, Lifei Zhang, Fanyu Chen, Gang Tan, Dongxing Cheng, Xiuyan Han, Buxing Zheng, Lirong Mo, Guang |
| description | The electrochemical synthesis of chemicals from carbon dioxide, which is an easily available and renewable carbon resource, is of great importance. However, to achieve high product selectivity for desirable C2 products like ethylene is a big challenge. Here we design Cu nanosheets with nanoscaled defects (2–14 nm) for the electrochemical production of ethylene from carbon dioxide. A high ethylene Faradaic efficiency of 83.2% is achieved. It is proved that the nanoscaled defects can enrich the reaction intermediates and hydroxyl ions on the electrocatalyst, thus promoting C–C coupling for ethylene formation. |
| doi_str_mv | 10.1021/jacs.0c06420 |
| format | Article |
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Am. Chem. Soc</addtitle><description>The electrochemical synthesis of chemicals from carbon dioxide, which is an easily available and renewable carbon resource, is of great importance. However, to achieve high product selectivity for desirable C2 products like ethylene is a big challenge. Here we design Cu nanosheets with nanoscaled defects (2–14 nm) for the electrochemical production of ethylene from carbon dioxide. A high ethylene Faradaic efficiency of 83.2% is achieved. 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| title | Highly Electrocatalytic Ethylene Production from CO2 on Nanodefective Cu Nanosheets |
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