A rigorous statistical analysis of errors incurred in the study of intermolecular fast-exchange equilibria by NMR spectroscopy

A detailed analysis of the algorithms used in the analysis of NMR fast-exchange equilibria is made. It is shown that, in a system of step-wise equilibria of the type A + B ⇌ AB, AB + B ⇌ AB 2, …, AB n−1 + B ⇌ AB n , the most efficient way to solve the resulting system of equations is to solve for [B...

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Veröffentlicht in:	Journal of magnetic resonance (1969) 1986-10, Vol.69 (3), p.467-475
Hauptverfasser:	Johnston, Milton D, Marchand, Alan P, Earlywine, A.E
Format:	Artikel
Sprache:	eng
Schlagworte:	Atomic and molecular physics Exact sciences and technology Molecular properties and interactions with photons Nuclear resonance and relaxation Physics
Online-Zugang:	Volltext
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