The Cyclopropane Ring as a Reporter of Radical Leaving-Group Reactivity for Ni-Catalyzed C(sp3)–O Arylation

The ability to understand and predict reactivity is essential for the development of new reactions. In the context of Ni-catalyzed C­(sp3)–O functionalization, we have developed a unique strategy employing activated cyclopropanols to aid the design and optimization of a redox-active leaving group fo...

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Veröffentlicht in:Journal of the American Chemical Society 2020-07, Vol.142 (30), p.13246-13254
Hauptverfasser: Mills, L. Reginald, Monteith, John J, dos Passos Gomes, Gabriel, Aspuru-Guzik, Alán, Rousseaux, Sophie A. L
Format: Artikel
Sprache:eng
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