Synthesis and stereoisomerism of [n]cyclo-2,9-phenanthrenylene congeners possessing alternating E/Z- and R/S-biaryl linkages

The synthesis and cyclostereoisomerism of [n]cyclo-2,9-phenanthrenylenes ([n]CPhen2,9, n = 4, 6 and 8), possessing hybrid E/Z- and R/S-biaryl linkages, were elaborated. The dimer of a phenanthrene derivative was used as a starting material and underwent Ni-mediated Yamamoto-type coupling to afford [...

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Veröffentlicht in:Organic & biomolecular chemistry 2020-07, Vol.18 (26), p.4949-4955
Hauptverfasser: Yang, Yong, Nanjo, Yuki, Isobe, Hiroyuki, Sato, Sota
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Sprache:eng
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