Allenes for Versatile Iron-Catalyzed C–H Activation by Weak O‑Coordination: Mechanistic Insights by Kinetics, Intermediate Isolation, and Computation

The iron-catalyzed hydroarylation of allenes was accomplished by weak phenone assistance. The C–H activation proceeded with excellent efficacy and high ortho-regioselectivity in proximity to the weakly coordinating carbonyl group for a range of substituted phenones and allenes. Detailed mechanistic...

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Veröffentlicht in:	Journal of the American Chemical Society 2020-07, Vol.142 (30), p.13102-13111
Hauptverfasser:	Messinis, Antonis M, Finger, Lars H, Hu, Lianrui, Ackermann, Lutz
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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