Analytical and Sensory Characterization of the Stereoisomers of 3‑Mercaptocycloalkanones and 3‑Mercaptocycloalkanols

3-Mercaptocycloalkanones and 3-mercaptocycloalkanols (chain lengths C5–C7) were obtained by addition of thioacetic acid to the respective 2-cycloalken-1-ones and subsequent enzyme-mediated hydrolysis and reduction with LiAlH4, respectively. The stereoisomers were separated via capillary gas chromato...

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Veröffentlicht in:	Journal of agricultural and food chemistry 2020-07, Vol.68 (27), p.7184-7193
Hauptverfasser:	Wakabayashi, Motoko, Wakabayashi, Hidehiko, Riegel, Anja Devenie, Eisenreich, Wolfgang, Engel, Karl-Heinz
Format:	Artikel
Sprache:	eng
Schlagworte:	Adult Chemistry and Biology of Aroma and Taste Cycloparaffins - chemistry Cycloparaffins - metabolism Female Gas Chromatography-Mass Spectrometry Humans Magnetic Resonance Spectroscopy Male Middle Aged Molecular Structure Odorants - analysis Olfactometry Smell Stereoisomerism Sulfhydryl Compounds - chemistry Sulfhydryl Compounds - metabolism Volatile Organic Compounds - chemistry Volatile Organic Compounds - metabolism
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