Spin crossover properties of Fe(III) complexes in [Fe (bzacen)(tvp)]BPh4·nSolv chain structures: EPR study

Two types of Fe(III) polynuclear iron(III) 1D‐chain coordination compounds of the general formula [Fe (L)(tvp)]BPh4 nSolv, where L = dianion of N,N′‐ethylenebis (benzoylacetylacetone)2,2′‐imine (bzacen), tvp = 1,2‐di(4‐pyridyl)ethylene were synthesized and studied by the electron paramagnetic resona...

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Veröffentlicht in:	Magnetic resonance in chemistry 2020-10, Vol.58 (10), p.949-956
Hauptverfasser:	Ivanova, Tatyana A., Ovchinnikov, Igor V., Turanova, Olga A., Bazan, Leah V., Shustov, Vladimir A., Batulin, Ruslan G., Cherosov, Mikhail A.
Format:	Artikel
Sprache:	eng
Schlagworte:	Anions Chains Chemical precipitation Coordination compounds Electron paramagnetic resonance Energy levels EPR spectroscopy Iron iron(III) complexes local ligand field Magnetic permeability Spin transition spin‐crossover transition Temperature dependence
Online-Zugang:	Volltext
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