More on the electropolymerization of styrene
The cathodic reduction of styrene in acetonitrile and tetra-n-butylammonium tetrafluoroborate is discussed. A well defined voltammetric wave was obtained at E p = −2.8 V and its study reveals irreversible electron transfer as the first step in the electrochemical reaction. The polystyrene forms on t...
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| Veröffentlicht in: | Polymer (Guilford) 1986-08, Vol.27 (8), p.1304-1306 |
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| container_title | Polymer (Guilford) |
| container_volume | 27 |
| creator | Ortega, Jose M Menolasina, Sabino de Márquez, Olga Pérez Márquez, Jairo |
| description | The cathodic reduction of styrene in acetonitrile and tetra-n-butylammonium tetrafluoroborate is discussed. A well defined voltammetric wave was obtained at
E
p = −2.8 V and its study reveals irreversible electron transfer as the first step in the electrochemical reaction. The polystyrene forms on the platinum electrode surface (with a molecular weight of 10
6) and it was possible to find conditions (galvanostatic electrolysis in
CHCl
3
n-Bu
4
NBF
4
) where its production rate was increased more than 70 times compared with the first potentiostatic electrolyses. |
| doi_str_mv | 10.1016/0032-3861(86)90023-6 |
| format | Article |
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E
p = −2.8 V and its study reveals irreversible electron transfer as the first step in the electrochemical reaction. The polystyrene forms on the platinum electrode surface (with a molecular weight of 10
6) and it was possible to find conditions (galvanostatic electrolysis in
CHCl
3
n-Bu
4
NBF
4
) where its production rate was increased more than 70 times compared with the first potentiostatic electrolyses.</description><identifier>ISSN: 0032-3861</identifier><identifier>EISSN: 1873-2291</identifier><identifier>DOI: 10.1016/0032-3861(86)90023-6</identifier><language>eng</language><publisher>Elsevier Ltd</publisher><subject>cathodic electropolymerization ; cathodic reduction ; electrochemical polymerization ; electrochemical reduction ; electropolymerization ; styrene</subject><ispartof>Polymer (Guilford), 1986-08, Vol.27 (8), p.1304-1306</ispartof><rights>1986</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c432t-e98b0d485998b2a0f0cd46930e3a3b5a528e8e2154e74e6bbfd4613f4cd79fc83</citedby><cites>FETCH-LOGICAL-c432t-e98b0d485998b2a0f0cd46930e3a3b5a528e8e2154e74e6bbfd4613f4cd79fc83</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/0032-3861(86)90023-6$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3550,27924,27925,45995</link.rule.ids></links><search><creatorcontrib>Ortega, Jose M</creatorcontrib><creatorcontrib>Menolasina, Sabino</creatorcontrib><creatorcontrib>de Márquez, Olga Pérez</creatorcontrib><creatorcontrib>Márquez, Jairo</creatorcontrib><title>More on the electropolymerization of styrene</title><title>Polymer (Guilford)</title><description>The cathodic reduction of styrene in acetonitrile and tetra-n-butylammonium tetrafluoroborate is discussed. A well defined voltammetric wave was obtained at
E
p = −2.8 V and its study reveals irreversible electron transfer as the first step in the electrochemical reaction. The polystyrene forms on the platinum electrode surface (with a molecular weight of 10
6) and it was possible to find conditions (galvanostatic electrolysis in
CHCl
3
n-Bu
4
NBF
4
) where its production rate was increased more than 70 times compared with the first potentiostatic electrolyses.</description><subject>cathodic electropolymerization</subject><subject>cathodic reduction</subject><subject>electrochemical polymerization</subject><subject>electrochemical reduction</subject><subject>electropolymerization</subject><subject>styrene</subject><issn>0032-3861</issn><issn>1873-2291</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1986</creationdate><recordtype>article</recordtype><recordid>eNqNkE1LxDAQhoMoWFf_gYeeRMFqvppNLoIsfsGKFz2HNJ1gpNusSVeov96sFY_iaQbmeV-YB6Fjgi8IJuISY0YrJgU5leJMYUxZJXZQQeScVZQqsouKX2QfHaT0hjNUU16g88cQoQx9ObxCCR3YIYZ16MYVRP9pBp8vwZVpGCP0cIj2nOkSHP3MGXq5vXle3FfLp7uHxfWyspzRoQIlG9xyWau8UIMdti0XimFghjW1qakECZTUHOYcRNO4fCbMcdvOlbOSzdDJ1LuO4X0DadArnyx0nekhbJKmnBCpKPsfSGqaQT6BNoaUIji9jn5l4qgJ1luHeitIbwVpKfS3Qy1y7GqKQf72w0PUyXroLbQ-ZlW6Df7vgi8q6nda</recordid><startdate>19860801</startdate><enddate>19860801</enddate><creator>Ortega, Jose M</creator><creator>Menolasina, Sabino</creator><creator>de Márquez, Olga Pérez</creator><creator>Márquez, Jairo</creator><general>Elsevier Ltd</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8FD</scope><scope>F28</scope><scope>FR3</scope><scope>7SR</scope><scope>JG9</scope></search><sort><creationdate>19860801</creationdate><title>More on the electropolymerization of styrene</title><author>Ortega, Jose M ; Menolasina, Sabino ; de Márquez, Olga Pérez ; Márquez, Jairo</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c432t-e98b0d485998b2a0f0cd46930e3a3b5a528e8e2154e74e6bbfd4613f4cd79fc83</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1986</creationdate><topic>cathodic electropolymerization</topic><topic>cathodic reduction</topic><topic>electrochemical polymerization</topic><topic>electrochemical reduction</topic><topic>electropolymerization</topic><topic>styrene</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ortega, Jose M</creatorcontrib><creatorcontrib>Menolasina, Sabino</creatorcontrib><creatorcontrib>de Márquez, Olga Pérez</creatorcontrib><creatorcontrib>Márquez, Jairo</creatorcontrib><collection>CrossRef</collection><collection>Technology Research Database</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>Engineered Materials Abstracts</collection><collection>Materials Research Database</collection><jtitle>Polymer (Guilford)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ortega, Jose M</au><au>Menolasina, Sabino</au><au>de Márquez, Olga Pérez</au><au>Márquez, Jairo</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>More on the electropolymerization of styrene</atitle><jtitle>Polymer (Guilford)</jtitle><date>1986-08-01</date><risdate>1986</risdate><volume>27</volume><issue>8</issue><spage>1304</spage><epage>1306</epage><pages>1304-1306</pages><issn>0032-3861</issn><eissn>1873-2291</eissn><abstract>The cathodic reduction of styrene in acetonitrile and tetra-n-butylammonium tetrafluoroborate is discussed. A well defined voltammetric wave was obtained at
E
p = −2.8 V and its study reveals irreversible electron transfer as the first step in the electrochemical reaction. The polystyrene forms on the platinum electrode surface (with a molecular weight of 10
6) and it was possible to find conditions (galvanostatic electrolysis in
CHCl
3
n-Bu
4
NBF
4
) where its production rate was increased more than 70 times compared with the first potentiostatic electrolyses.</abstract><pub>Elsevier Ltd</pub><doi>10.1016/0032-3861(86)90023-6</doi><tpages>3</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0032-3861 |
| ispartof | Polymer (Guilford), 1986-08, Vol.27 (8), p.1304-1306 |
| issn | 0032-3861 1873-2291 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_24118923 |
| source | ScienceDirect Journals (5 years ago - present) |
| subjects | cathodic electropolymerization cathodic reduction electrochemical polymerization electrochemical reduction electropolymerization styrene |
| title | More on the electropolymerization of styrene |
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