Strong stretching theory for pH-responsive polyelectrolyte brushes in large salt concentrations

In this paper, we develop a theory for describing the thermodynamics, configuration, and electrostatics of strongly-stretched, pH-responsive polyelectrolyte (PE) brushes in the presence of large salt concentrations. The aim of the paper, therefore, is to study the properties of a PE brush in a salt...

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Veröffentlicht in:	Physical chemistry chemical physics : PCCP 2020-06, Vol.22 (24), p.13536-13553
Hauptverfasser:	Etha, Sai Ankit, Sivasankar, Vishal Sankar, Sachar, Harnoor Singh, Das, Siddhartha
Format:	Artikel
Sprache:	eng
Schlagworte:	Brushes Computer simulation Configurations Correlation Density Dipoles Electric double layer Electrostatics Free energy Monomers Polarization Polyelectrolytes Size effects Solvents Stretching Theory
Online-Zugang:	Volltext
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