Bioinspired Multifunctional Organic Transistors Based on Natural Chlorophyll/Organic Semiconductors

Inspired by the photosynthesis process of natural plants, multifunctional transistors based on natural biomaterial chlorophyll and organic semiconductors (OSCs) are reported. Functions as photodetectors (PDs) and light‐stimulated synaptic transistors (LSSTs) can be switched by gate voltage. As PDs, the devices exhibit ultrahigh photoresponsivity up to 2 × 106 A W−1, detectivity of 6 × 1015 Jones, and Iphoto/Idark ratio of 2.7 × 106, which make them among the best reported organic PDs. As LSSTs, important synaptic functions similar to biological synapses are demonstrated, together with a dynamic learning and forgetting process and image‐processing function. Significantly, benefiting from the ultrahigh photosensitivity of chlorophyll, the lowest operating voltage and energy consumption of the LSSTs can be 10−5 V and 0.25 fJ, respectively. The devices also exhibit high flexibility and long‐term air stability. This work provides a new guide for developing organic electronics based on natural biomaterials. Bioinspired multifunctional organic transistors based on natural chlorophyll and organic semiconductors are fabricated. Phototdetection and light‐stimulated synaptic transistor function can be realized by the single device under gate‐voltage control. The devices show excellent photoresponsivity up to 2 × 106 A W−1 as photodetectors and ultralow operating voltage of 10–5 V as synaptic devices.