Metal–Organic Material Polymer Coatings for Enhanced Gas Sorption Performance and Hydrolytic Stability under Humid Conditions

Metal–Organic Material Polymer Coatings for Enhanced Gas Sorption Performance and Hydrolytic Stability under Humid Conditions

Physisorbent metal–organic materials (MOMs) have shown benchmark performance for highly selective CO2 capture from bulk and trace gas mixtures. However, gas stream moisture can be detrimental to both adsorbent performance and hydrolytic stability. One of the most effective methods to solve this issu...

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Veröffentlicht in:ACS applied materials & interfaces 2020-07, Vol.12 (30), p.33759-33764
Hauptverfasser: Madden, David G, Albadarin, Ahmad B, O’Nolan, Daniel, Cronin, Patrick, Perry, John J, Solomon, Samuel, Curtin, Teresa, Khraisheh, Majeda, Zaworotko, Michael J, Walker, Gavin M
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Energy, Environmental, and Catalysis Applications
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container_end_page 33764
container_issue 30
container_start_page 33759
container_title ACS applied materials & interfaces
container_volume 12
creator Madden, David G
Albadarin, Ahmad B
O’Nolan, Daniel
Cronin, Patrick
Perry, John J
Solomon, Samuel
Curtin, Teresa
Khraisheh, Majeda
Zaworotko, Michael J
Walker, Gavin M
description Physisorbent metal–organic materials (MOMs) have shown benchmark performance for highly selective CO2 capture from bulk and trace gas mixtures. However, gas stream moisture can be detrimental to both adsorbent performance and hydrolytic stability. One of the most effective methods to solve this issue is to transform the adsorbent surface from hydrophilic to hydrophobic. Herein, we present a facile approach for coating MOMs with organic polymers to afford improved hydrophobicity and hydrolytic stability under humid conditions. The impact of gas stream moisture on CO2 capture for the composite materials was found to be negligible under both bulk and trace CO2 capture conditions with significant improvements in regeneration times and energy requirements.
doi_str_mv 10.1021/acsami.0c08078
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title Metal–Organic Material Polymer Coatings for Enhanced Gas Sorption Performance and Hydrolytic Stability under Humid Conditions
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