Pnicogen Bonds Pairing an Anionic Lewis Acid with Neutral and Anionic Bases

The complexation process between anionic ZCl4- (Z = P, As, Sb) and neutral NCH and pyridine, as well as the CN- anion, are studied in both the gas phase and aqueous solution by high-level ab initio calculations. Despite the absence of a positively charged σ-hole on ZCl4-, a pnicogen bond holds all o...

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Veröffentlicht in:	The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Molecules, spectroscopy, kinetics, environment, & general theory, 2020-06, Vol.124 (24), p.4998-5006
Hauptverfasser:	Scheiner, Steve, Wysoki Ski, Rafa, Michalczyk, Mariusz, Zierkiewicz, Wiktor
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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