Reactive Extraction Enhanced by Synergic Microwave Heating: Furfural Yield Boost in Biphasic Systems
Reactive extraction is an emerging operation in the industry, particularly in biorefining. Here, reactive extraction was demonstrated, enhanced by microwave irradiation to selectively heat the reactive phase (for efficient reaction) without unduly heating the extractive phase (for efficient extracti...
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| Veröffentlicht in: | ChemSusChem 2020-07, Vol.13 (14), p.3589-3593 |
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| creator | Ricciardi, Luca Verboom, Willem Lange, Jean‐Paul Huskens, Jurriaan |
| description | Reactive extraction is an emerging operation in the industry, particularly in biorefining. Here, reactive extraction was demonstrated, enhanced by microwave irradiation to selectively heat the reactive phase (for efficient reaction) without unduly heating the extractive phase (for efficient extraction). These conditions aimed at maximizing the asymmetries in dielectric constants and volumes of the reaction and extraction phases, which resulted in an asymmetric thermal response of the two phases. The efficiency improvement was demonstrated by dehydrating xylose (5 wt % in water) to furfural with an optimal yield of approximately 80 mol % compared with 60–65 mol % under conventional biphasic conditions, which corresponds to approximately 50 % reduction of byproducts.
It's not just a phase: Reactive extraction of xylose to furfural is boosted by a synergic combination of microwave heating and biphasic operation to deliver a hot aqueous phase for reaction and a colder organic phase for extraction. |
| doi_str_mv | 10.1002/cssc.202000966 |
| format | Article |
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It's not just a phase: Reactive extraction of xylose to furfural is boosted by a synergic combination of microwave heating and biphasic operation to deliver a hot aqueous phase for reaction and a colder organic phase for extraction.</description><subject>Asymmetry</subject><subject>biomass</subject><subject>biphasic</subject><subject>Chemistry</subject><subject>Chemistry, Multidisciplinary</subject><subject>Communication</subject><subject>Communications</subject><subject>Dehydration</subject><subject>Furfural</subject><subject>Green & Sustainable Science & Technology</subject><subject>Heating</subject><subject>microwave chemistry</subject><subject>Optimization</subject><subject>Physical Sciences</subject><subject>Science & Technology</subject><subject>Science & Technology - Other Topics</subject><subject>synergy</subject><subject>Thermal response</subject><issn>1864-5631</issn><issn>1864-564X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><sourceid>24P</sourceid><sourceid>WIN</sourceid><sourceid>AOWDO</sourceid><recordid>eNqNkc-L1DAcxYso7rp69SgBL4LMmKRJ2ngQ3DLrCiuCo6CnkKbfzmTpJGPS7tr_3tQZ64-L5pIv5PMe35eXZY8JXhKM6QsTo1lSTDHGUog72SkpBVtwwT7fneecnGQPYrzGWEzQ_ewkp4xJKtlp1nwAbXp7A2j1rQ_T6B1aua12BhpUj2g9Oggba9A7a4K_1Ym8BN1bt3mJLobQDkF36IuFrkHn3sceWYfO7X6rY9Ksx9jDLj7M7rW6i_DoeJ9lny5WH6vLxdX7N2-r11cLwzEXCyOE0EwQrBkTgHFRsBxM3WowpalJTVvSFrrRstGMt40sW4kZITnQkjQYN_lZ9urgux_qHTQGXIrUqX2wOx1G5bVVf744u1Ubf6MKJgUvZTJ4djQI_usAsVc7Gw10nXbgh6gow4IXvCQioU__Qq_9EFyKlyjKi4LLkiRqeaDS38UYoJ2XIVhNBaqpQDUXmARPfo8w4z8bS0B5AG6h9m00FlJTM5ZcOKMlxz8OqWyvp0YrP7g-SZ__vzTR8kjbDsZ_7K2q9br6leI7jpTJ8A</recordid><startdate>20200722</startdate><enddate>20200722</enddate><creator>Ricciardi, Luca</creator><creator>Verboom, Willem</creator><creator>Lange, Jean‐Paul</creator><creator>Huskens, Jurriaan</creator><general>Wiley</general><general>Wiley Subscription Services, Inc</general><general>John Wiley and Sons Inc</general><scope>24P</scope><scope>WIN</scope><scope>AOWDO</scope><scope>BLEPL</scope><scope>DTL</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>K9.</scope><scope>7X8</scope><scope>5PM</scope><orcidid>https://orcid.org/0000-0001-6567-2957</orcidid><orcidid>https://orcid.org/0000-0002-4596-9179</orcidid><orcidid>https://orcid.org/0000-0002-6863-8655</orcidid><orcidid>https://orcid.org/0000-0001-5110-8386</orcidid></search><sort><creationdate>20200722</creationdate><title>Reactive Extraction Enhanced by Synergic Microwave Heating: Furfural Yield Boost in Biphasic Systems</title><author>Ricciardi, Luca ; 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| subjects | Asymmetry biomass biphasic Chemistry Chemistry, Multidisciplinary Communication Communications Dehydration Furfural Green & Sustainable Science & Technology Heating microwave chemistry Optimization Physical Sciences Science & Technology Science & Technology - Other Topics synergy Thermal response |
| title | Reactive Extraction Enhanced by Synergic Microwave Heating: Furfural Yield Boost in Biphasic Systems |
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