Electronic Spillover from a Metallic Nanoparticle: Can Simple Electrochemical Electron Transfer Processes Be Catalyzed by Electronic Coupling of a Molecular Scale Gold Nanoparticle Simultaneously to the Redox Molecule and the Electrode?

Electrochemical electron transfer (ET) of transition metal complexes or redox metalloproteins can be catalyzed by more than an order of magnitude by molecular scale metallic nanoparticles (NPs), often rationalized by concentration enhancement of the redox molecules in the interfacial region, but col...

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Veröffentlicht in:Journal of the American Chemical Society 2020-06, Vol.142 (24), p.10646-10658
Hauptverfasser: Shermukhamedov, Shokirbek A, Nazmutdinov, Renat R, Zinkicheva, Tamara T, Bronshtein, Michael D, Zhang, Jingdong, Mao, Bingwei, Tian, Zhongqun, Yan, Jiawei, Wu, De-Yin, Ulstrup, Jens
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Sprache:eng
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