Photo-activated CO-release in the amino tungsten Fischer carbene complex, [(CO)5WC(NC4H8)Me], picosecond time resolved infrared spectroscopy, time-dependent density functional theory, and an antimicrobial study

Picosecond time-resolved infrared spectroscopy was used to probe the photo-induced early state dynamics preceding CO loss in the Fischer carbene complex, [(CO)5WC(NC4H8)CH3]. Time-dependent density functional theory calculations were employed to help in understanding the photochemical and photophysi...

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Veröffentlicht in:	Journal of inorganic biochemistry 2020-07, Vol.208, p.111071-111071, Article 111071
Hauptverfasser:	McMahon, Suzanne, Rajagopal, Ashwene, Amirjalayer, Saeed, Halpin, Yvonne, Fitzgerald-Hughes, Deirdre, Buma, Wybren Jan, Woutersen, Sander, Long, Conor, Pryce, Mary T.
Format:	Artikel
Sprache:	eng
Schlagworte:	Antimicrobial Photochemical CO-loss Picosecond time-resolved infrared spectroscopy Tungsten based Fischer carbene
Online-Zugang:	Volltext
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