Synthesis and Structures of Polyphenylphenanthrenes

1,2,3,4,5,6,7,8‐Octaphenylphenanthrene (4) and decaphenylphenanthrene (5) were prepared by very short syntheses (two or three steps) from tetraphenylfuran and polybrominated benzene derivatives. The X‐ray structures of compounds 4 and 5 show them to be quite crowded, with the phenanthrene cores twis...

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Veröffentlicht in:	Chemistry : a European journal 2020-07, Vol.26 (38), p.8458-8464
Hauptverfasser:	Xiao, Yonglong, Mague, Joel T., Donahue, James P., Wilson, Laura J., Kraml, Christina M., Pascal, Robert A.
Format:	Artikel
Sprache:	eng
Schlagworte:	Activation energy arenes Benzene Chemistry Computer applications Free energy Phenanthrene polycyclic aromatic hydrocarbons polyphenyl aromatic compounds Racemization Room temperature strained molecules
Online-Zugang:	Volltext
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