Enhancement of NOx photo-oxidation by Fe- and Cu-doped blue TiO2
The present work is focused on the removal of NOx with reduced blue TiO 2 with Fe (blue Fe-TiO 2 )- and Cu (blue Cu-TiO 2 )-doped photocatalyst. TiO 2 was reduced via lithium in EDA (blue TiO 2 ). Fe and Cu ions were doped in the reduced TiO 2 (blue Fe-TiO 2 and blue Cu-TiO 2 ). The material resulte...
Gespeichert in:
| Veröffentlicht in: | Environmental science and pollution research international 2020-07, Vol.27 (21), p.26702-26713 |
|---|---|
| Hauptverfasser: | , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 26713 |
|---|---|
| container_issue | 21 |
| container_start_page | 26702 |
| container_title | Environmental science and pollution research international |
| container_volume | 27 |
| creator | Martinez-Oviedo, Adriana Ray, Schindra Kumar Joshi, Bhupendra Lee, Soo Wohn |
| description | The present work is focused on the removal of NOx with reduced blue TiO
2
with Fe (blue Fe-TiO
2
)- and Cu (blue Cu-TiO
2
)-doped photocatalyst. TiO
2
was reduced via lithium in EDA (blue TiO
2
). Fe and Cu ions were doped in the reduced TiO
2
(blue Fe-TiO
2
and blue Cu-TiO
2
). The material resulted in a core-shell structure of amorphous and anatase phase. XPS suggests the existence of Ti
3+
species and oxygen vacancies within the structure of TiO
2
. Additionally, valence bond (VB)-XPS shows the generation of intermediate levels at the band edge of the doped photocatalyst. Photocurrent, electrochemical impedance spectroscopy and cyclic voltammetry confirmed the enhanced charge-separation process in doped reduced TiO
2
. The photocatalysts were tested for the photo-oxidation of NOx. Blue Fe-TiO
2
reveals the efficiency of 70% for NO elimination and 44.74% for NO
2
formation. The improved efficiency of the doped photocatalyst is related to the re-engineered structure with Ti
3+
species, oxygen vacancies, and charge traps. Electron spin resonance (ESR) measurement was carried out for blue Fe-TiO
2
to confirm the formation of reactive oxygen species (ROS). Furthermore, ion chromatography was used to investigate the mechanism of NOx oxidation. In conclusion, the doped blue TiO
2
has a strong tendency to photo-oxidize NOx gasses. |
| doi_str_mv | 10.1007/s11356-020-09078-4 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_2399835453</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2419555336</sourcerecordid><originalsourceid>FETCH-LOGICAL-c389t-e28b317ea2e20e67ff51d30a349663b27ad5d0543b36caae4c2a7224110fa9f23</originalsourceid><addsrcrecordid>eNp9kE9LwzAYh4MoOKdfwFPAi5do_jbNTRmbCsNd5jmk7VvX0SWzaWH79kYrCB48vZfn9_DyIHTN6B2jVN9HxoTKCOWUUEN1TuQJmrCMSaKlMadoQo2UhAkpz9FFjFuaSMP1BD3M_cb5Enbgexxq_Lo64P0m9IGEQ1O5vgkeF0e8AIKdr_BsIFXYQ4WLdgC8blb8Ep3Vro1w9XOn6G0xX8-eyXL19DJ7XJJS5KYnwPNCMA2OA6eQ6bpWrBLUCWmyTBRcu0pVVElRiKx0DmTJneZcMkZrZ2oupuh29O678DFA7O2uiSW0rfMQhmi5MCYXSiqR0Js_6DYMnU_f2SQ0SiUmSxQfqbILMXZQ233X7Fx3tIzar6h2jGpTKvsd1co0EuMoJti_Q_er_mf1CV2Ldug</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2419555336</pqid></control><display><type>article</type><title>Enhancement of NOx photo-oxidation by Fe- and Cu-doped blue TiO2</title><source>Springer Nature - Complete Springer Journals</source><creator>Martinez-Oviedo, Adriana ; Ray, Schindra Kumar ; Joshi, Bhupendra ; Lee, Soo Wohn</creator><creatorcontrib>Martinez-Oviedo, Adriana ; Ray, Schindra Kumar ; Joshi, Bhupendra ; Lee, Soo Wohn</creatorcontrib><description>The present work is focused on the removal of NOx with reduced blue TiO
2
with Fe (blue Fe-TiO
2
)- and Cu (blue Cu-TiO
2
)-doped photocatalyst. TiO
2
was reduced via lithium in EDA (blue TiO
2
). Fe and Cu ions were doped in the reduced TiO
2
(blue Fe-TiO
2
and blue Cu-TiO
2
). The material resulted in a core-shell structure of amorphous and anatase phase. XPS suggests the existence of Ti
3+
species and oxygen vacancies within the structure of TiO
2
. Additionally, valence bond (VB)-XPS shows the generation of intermediate levels at the band edge of the doped photocatalyst. Photocurrent, electrochemical impedance spectroscopy and cyclic voltammetry confirmed the enhanced charge-separation process in doped reduced TiO
2
. The photocatalysts were tested for the photo-oxidation of NOx. Blue Fe-TiO
2
reveals the efficiency of 70% for NO elimination and 44.74% for NO
2
formation. The improved efficiency of the doped photocatalyst is related to the re-engineered structure with Ti
3+
species, oxygen vacancies, and charge traps. Electron spin resonance (ESR) measurement was carried out for blue Fe-TiO
2
to confirm the formation of reactive oxygen species (ROS). Furthermore, ion chromatography was used to investigate the mechanism of NOx oxidation. In conclusion, the doped blue TiO
2
has a strong tendency to photo-oxidize NOx gasses.</description><identifier>ISSN: 0944-1344</identifier><identifier>EISSN: 1614-7499</identifier><identifier>DOI: 10.1007/s11356-020-09078-4</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Amorphous materials ; Anatase ; Aquatic Pollution ; Atmospheric Protection/Air Quality Control/Air Pollution ; Core-shell structure ; Earth and Environmental Science ; Ecotoxicology ; Electrochemical impedance spectroscopy ; Electrochemistry ; Electron paramagnetic resonance ; Electron spin ; Electron spin resonance ; Electrons ; Environment ; Environmental Chemistry ; Environmental Health ; Environmental science ; Lithium ; Nitrogen dioxide ; Oxidation ; Oxygen ; Photocatalysts ; Photoelectric effect ; Photoelectric emission ; Photooxidation ; Reactive oxygen species ; Research Article ; Spectroscopy ; Spin resonance ; Titanium dioxide ; Vacancies ; Waste Water Technology ; Water Management ; Water Pollution Control</subject><ispartof>Environmental science and pollution research international, 2020-07, Vol.27 (21), p.26702-26713</ispartof><rights>Springer-Verlag GmbH Germany, part of Springer Nature 2020</rights><rights>Springer-Verlag GmbH Germany, part of Springer Nature 2020.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c389t-e28b317ea2e20e67ff51d30a349663b27ad5d0543b36caae4c2a7224110fa9f23</citedby><cites>FETCH-LOGICAL-c389t-e28b317ea2e20e67ff51d30a349663b27ad5d0543b36caae4c2a7224110fa9f23</cites><orcidid>0000-0002-9582-8956</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11356-020-09078-4$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11356-020-09078-4$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Martinez-Oviedo, Adriana</creatorcontrib><creatorcontrib>Ray, Schindra Kumar</creatorcontrib><creatorcontrib>Joshi, Bhupendra</creatorcontrib><creatorcontrib>Lee, Soo Wohn</creatorcontrib><title>Enhancement of NOx photo-oxidation by Fe- and Cu-doped blue TiO2</title><title>Environmental science and pollution research international</title><addtitle>Environ Sci Pollut Res</addtitle><description>The present work is focused on the removal of NOx with reduced blue TiO
2
with Fe (blue Fe-TiO
2
)- and Cu (blue Cu-TiO
2
)-doped photocatalyst. TiO
2
was reduced via lithium in EDA (blue TiO
2
). Fe and Cu ions were doped in the reduced TiO
2
(blue Fe-TiO
2
and blue Cu-TiO
2
). The material resulted in a core-shell structure of amorphous and anatase phase. XPS suggests the existence of Ti
3+
species and oxygen vacancies within the structure of TiO
2
. Additionally, valence bond (VB)-XPS shows the generation of intermediate levels at the band edge of the doped photocatalyst. Photocurrent, electrochemical impedance spectroscopy and cyclic voltammetry confirmed the enhanced charge-separation process in doped reduced TiO
2
. The photocatalysts were tested for the photo-oxidation of NOx. Blue Fe-TiO
2
reveals the efficiency of 70% for NO elimination and 44.74% for NO
2
formation. The improved efficiency of the doped photocatalyst is related to the re-engineered structure with Ti
3+
species, oxygen vacancies, and charge traps. Electron spin resonance (ESR) measurement was carried out for blue Fe-TiO
2
to confirm the formation of reactive oxygen species (ROS). Furthermore, ion chromatography was used to investigate the mechanism of NOx oxidation. In conclusion, the doped blue TiO
2
has a strong tendency to photo-oxidize NOx gasses.</description><subject>Amorphous materials</subject><subject>Anatase</subject><subject>Aquatic Pollution</subject><subject>Atmospheric Protection/Air Quality Control/Air Pollution</subject><subject>Core-shell structure</subject><subject>Earth and Environmental Science</subject><subject>Ecotoxicology</subject><subject>Electrochemical impedance spectroscopy</subject><subject>Electrochemistry</subject><subject>Electron paramagnetic resonance</subject><subject>Electron spin</subject><subject>Electron spin resonance</subject><subject>Electrons</subject><subject>Environment</subject><subject>Environmental Chemistry</subject><subject>Environmental Health</subject><subject>Environmental science</subject><subject>Lithium</subject><subject>Nitrogen dioxide</subject><subject>Oxidation</subject><subject>Oxygen</subject><subject>Photocatalysts</subject><subject>Photoelectric effect</subject><subject>Photoelectric emission</subject><subject>Photooxidation</subject><subject>Reactive oxygen species</subject><subject>Research Article</subject><subject>Spectroscopy</subject><subject>Spin resonance</subject><subject>Titanium dioxide</subject><subject>Vacancies</subject><subject>Waste Water Technology</subject><subject>Water Management</subject><subject>Water Pollution Control</subject><issn>0944-1344</issn><issn>1614-7499</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><recordid>eNp9kE9LwzAYh4MoOKdfwFPAi5do_jbNTRmbCsNd5jmk7VvX0SWzaWH79kYrCB48vZfn9_DyIHTN6B2jVN9HxoTKCOWUUEN1TuQJmrCMSaKlMadoQo2UhAkpz9FFjFuaSMP1BD3M_cb5Enbgexxq_Lo64P0m9IGEQ1O5vgkeF0e8AIKdr_BsIFXYQ4WLdgC8blb8Ep3Vro1w9XOn6G0xX8-eyXL19DJ7XJJS5KYnwPNCMA2OA6eQ6bpWrBLUCWmyTBRcu0pVVElRiKx0DmTJneZcMkZrZ2oupuh29O678DFA7O2uiSW0rfMQhmi5MCYXSiqR0Js_6DYMnU_f2SQ0SiUmSxQfqbILMXZQ233X7Fx3tIzar6h2jGpTKvsd1co0EuMoJti_Q_er_mf1CV2Ldug</recordid><startdate>20200701</startdate><enddate>20200701</enddate><creator>Martinez-Oviedo, Adriana</creator><creator>Ray, Schindra Kumar</creator><creator>Joshi, Bhupendra</creator><creator>Lee, Soo Wohn</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>7QL</scope><scope>7SN</scope><scope>7T7</scope><scope>7TV</scope><scope>7U7</scope><scope>7WY</scope><scope>7WZ</scope><scope>7X7</scope><scope>7XB</scope><scope>87Z</scope><scope>88E</scope><scope>88I</scope><scope>8AO</scope><scope>8C1</scope><scope>8FD</scope><scope>8FI</scope><scope>8FJ</scope><scope>8FK</scope><scope>8FL</scope><scope>ABUWG</scope><scope>AEUYN</scope><scope>AFKRA</scope><scope>ATCPS</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BEZIV</scope><scope>BHPHI</scope><scope>C1K</scope><scope>CCPQU</scope><scope>DWQXO</scope><scope>FR3</scope><scope>FRNLG</scope><scope>FYUFA</scope><scope>F~G</scope><scope>GHDGH</scope><scope>GNUQQ</scope><scope>HCIFZ</scope><scope>K60</scope><scope>K6~</scope><scope>K9.</scope><scope>L.-</scope><scope>M0C</scope><scope>M0S</scope><scope>M1P</scope><scope>M2P</scope><scope>M7N</scope><scope>P64</scope><scope>PATMY</scope><scope>PHGZM</scope><scope>PHGZT</scope><scope>PJZUB</scope><scope>PKEHL</scope><scope>PPXIY</scope><scope>PQBIZ</scope><scope>PQBZA</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>PYCSY</scope><scope>Q9U</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0002-9582-8956</orcidid></search><sort><creationdate>20200701</creationdate><title>Enhancement of NOx photo-oxidation by Fe- and Cu-doped blue TiO2</title><author>Martinez-Oviedo, Adriana ; Ray, Schindra Kumar ; Joshi, Bhupendra ; Lee, Soo Wohn</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c389t-e28b317ea2e20e67ff51d30a349663b27ad5d0543b36caae4c2a7224110fa9f23</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Amorphous materials</topic><topic>Anatase</topic><topic>Aquatic Pollution</topic><topic>Atmospheric Protection/Air Quality Control/Air Pollution</topic><topic>Core-shell structure</topic><topic>Earth and Environmental Science</topic><topic>Ecotoxicology</topic><topic>Electrochemical impedance spectroscopy</topic><topic>Electrochemistry</topic><topic>Electron paramagnetic resonance</topic><topic>Electron spin</topic><topic>Electron spin resonance</topic><topic>Electrons</topic><topic>Environment</topic><topic>Environmental Chemistry</topic><topic>Environmental Health</topic><topic>Environmental science</topic><topic>Lithium</topic><topic>Nitrogen dioxide</topic><topic>Oxidation</topic><topic>Oxygen</topic><topic>Photocatalysts</topic><topic>Photoelectric effect</topic><topic>Photoelectric emission</topic><topic>Photooxidation</topic><topic>Reactive oxygen species</topic><topic>Research Article</topic><topic>Spectroscopy</topic><topic>Spin resonance</topic><topic>Titanium dioxide</topic><topic>Vacancies</topic><topic>Waste Water Technology</topic><topic>Water Management</topic><topic>Water Pollution Control</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Martinez-Oviedo, Adriana</creatorcontrib><creatorcontrib>Ray, Schindra Kumar</creatorcontrib><creatorcontrib>Joshi, Bhupendra</creatorcontrib><creatorcontrib>Lee, Soo Wohn</creatorcontrib><collection>CrossRef</collection><collection>ProQuest Central (Corporate)</collection><collection>Bacteriology Abstracts (Microbiology B)</collection><collection>Ecology Abstracts</collection><collection>Industrial and Applied Microbiology Abstracts (Microbiology A)</collection><collection>Pollution Abstracts</collection><collection>Toxicology Abstracts</collection><collection>ABI/INFORM Collection</collection><collection>ABI/INFORM Global (PDF only)</collection><collection>Health & Medical Collection</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>ABI/INFORM Global (Alumni Edition)</collection><collection>Medical Database (Alumni Edition)</collection><collection>Science Database (Alumni Edition)</collection><collection>ProQuest Pharma Collection</collection><collection>Public Health Database</collection><collection>Technology Research Database</collection><collection>Hospital Premium Collection</collection><collection>Hospital Premium Collection (Alumni Edition)</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>ABI/INFORM Collection (Alumni Edition)</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest One Sustainability</collection><collection>ProQuest Central UK/Ireland</collection><collection>Agricultural & Environmental Science Collection</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Business Premium Collection</collection><collection>Natural Science Collection (ProQuest)</collection><collection>Environmental Sciences and Pollution Management</collection><collection>ProQuest One Community College</collection><collection>ProQuest Central Korea</collection><collection>Engineering Research Database</collection><collection>Business Premium Collection (Alumni)</collection><collection>Health Research Premium Collection</collection><collection>ABI/INFORM Global (Corporate)</collection><collection>Health Research Premium Collection (Alumni)</collection><collection>ProQuest Central Student</collection><collection>SciTech Premium Collection</collection><collection>ProQuest Business Collection (Alumni Edition)</collection><collection>ProQuest Business Collection</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>ABI/INFORM Professional Advanced</collection><collection>ABI/INFORM Global</collection><collection>Health & Medical Collection (Alumni Edition)</collection><collection>Medical Database</collection><collection>Science Database</collection><collection>Algology Mycology and Protozoology Abstracts (Microbiology C)</collection><collection>Biotechnology and BioEngineering Abstracts</collection><collection>Environmental Science Database</collection><collection>ProQuest Central (New)</collection><collection>ProQuest One Academic (New)</collection><collection>ProQuest Health & Medical Research Collection</collection><collection>ProQuest One Academic Middle East (New)</collection><collection>ProQuest One Health & Nursing</collection><collection>One Business (ProQuest)</collection><collection>ProQuest One Business (Alumni)</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>Environmental Science Collection</collection><collection>ProQuest Central Basic</collection><collection>MEDLINE - Academic</collection><jtitle>Environmental science and pollution research international</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Martinez-Oviedo, Adriana</au><au>Ray, Schindra Kumar</au><au>Joshi, Bhupendra</au><au>Lee, Soo Wohn</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Enhancement of NOx photo-oxidation by Fe- and Cu-doped blue TiO2</atitle><jtitle>Environmental science and pollution research international</jtitle><stitle>Environ Sci Pollut Res</stitle><date>2020-07-01</date><risdate>2020</risdate><volume>27</volume><issue>21</issue><spage>26702</spage><epage>26713</epage><pages>26702-26713</pages><issn>0944-1344</issn><eissn>1614-7499</eissn><abstract>The present work is focused on the removal of NOx with reduced blue TiO
2
with Fe (blue Fe-TiO
2
)- and Cu (blue Cu-TiO
2
)-doped photocatalyst. TiO
2
was reduced via lithium in EDA (blue TiO
2
). Fe and Cu ions were doped in the reduced TiO
2
(blue Fe-TiO
2
and blue Cu-TiO
2
). The material resulted in a core-shell structure of amorphous and anatase phase. XPS suggests the existence of Ti
3+
species and oxygen vacancies within the structure of TiO
2
. Additionally, valence bond (VB)-XPS shows the generation of intermediate levels at the band edge of the doped photocatalyst. Photocurrent, electrochemical impedance spectroscopy and cyclic voltammetry confirmed the enhanced charge-separation process in doped reduced TiO
2
. The photocatalysts were tested for the photo-oxidation of NOx. Blue Fe-TiO
2
reveals the efficiency of 70% for NO elimination and 44.74% for NO
2
formation. The improved efficiency of the doped photocatalyst is related to the re-engineered structure with Ti
3+
species, oxygen vacancies, and charge traps. Electron spin resonance (ESR) measurement was carried out for blue Fe-TiO
2
to confirm the formation of reactive oxygen species (ROS). Furthermore, ion chromatography was used to investigate the mechanism of NOx oxidation. In conclusion, the doped blue TiO
2
has a strong tendency to photo-oxidize NOx gasses.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s11356-020-09078-4</doi><tpages>12</tpages><orcidid>https://orcid.org/0000-0002-9582-8956</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0944-1344 |
| ispartof | Environmental science and pollution research international, 2020-07, Vol.27 (21), p.26702-26713 |
| issn | 0944-1344 1614-7499 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_2399835453 |
| source | Springer Nature - Complete Springer Journals |
| subjects | Amorphous materials Anatase Aquatic Pollution Atmospheric Protection/Air Quality Control/Air Pollution Core-shell structure Earth and Environmental Science Ecotoxicology Electrochemical impedance spectroscopy Electrochemistry Electron paramagnetic resonance Electron spin Electron spin resonance Electrons Environment Environmental Chemistry Environmental Health Environmental science Lithium Nitrogen dioxide Oxidation Oxygen Photocatalysts Photoelectric effect Photoelectric emission Photooxidation Reactive oxygen species Research Article Spectroscopy Spin resonance Titanium dioxide Vacancies Waste Water Technology Water Management Water Pollution Control |
| title | Enhancement of NOx photo-oxidation by Fe- and Cu-doped blue TiO2 |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-19T00%3A52%3A13IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Enhancement%20of%20NOx%20photo-oxidation%20by%20Fe-%20and%20Cu-doped%20blue%20TiO2&rft.jtitle=Environmental%20science%20and%20pollution%20research%20international&rft.au=Martinez-Oviedo,%20Adriana&rft.date=2020-07-01&rft.volume=27&rft.issue=21&rft.spage=26702&rft.epage=26713&rft.pages=26702-26713&rft.issn=0944-1344&rft.eissn=1614-7499&rft_id=info:doi/10.1007/s11356-020-09078-4&rft_dat=%3Cproquest_cross%3E2419555336%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2419555336&rft_id=info:pmid/&rfr_iscdi=true |