Carbon–Carbon Bond Forming Reactions Promoted by Aluminyl and Alumoxane Anions: Introducing the Ethenetetraolate Ligand

[K{Al(NONDipp)}]2 (NONDipp=[O(SiMe2NDipp)2]2−, Dipp=2,6‐iPr2C6H3) reacts with CS2 to afford the trithiocarbonate species [K(OEt2)][Al(NONDipp)(CS3)] 1 or the ethenetetrathiolate complex, [K{Al(NONDipp)(S2C)}]2 [3]2. The dimeric alumoxane [K{Al(NONDipp)(O)}]2 reacts with carbon monoxide to afford the...

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Veröffentlicht in:	Angewandte Chemie International Edition 2020-07, Vol.59 (31), p.12806-12810
Hauptverfasser:	Anker, Mathew D., McMullin, Claire L., Rajabi, Nasir A., Coles, Martyn P.
Format:	Artikel
Sprache:	eng
Schlagworte:	aluminyl anion Anions Carbon carbon disulfide Carbon monoxide Chemistry Chemistry, Multidisciplinary C−C bond formation ethenetetraolate ethylenetetrathiolate Ligands Physical Sciences Science & Technology
Online-Zugang:	Volltext
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