Enantioselective Synthesis of Functionalized Arenes by Nickel‐Catalyzed Site‐Selective Hydroarylation of 1,3‐Dienes with Aryl Boronates

A catalytic method for the site‐selective and enantioselective synthesis of functionalized arenes by the intermolecular hydroarylation of terminal and internal 1,3‐dienes with aryl pinacolato boronates is reported. The reactions are promoted by 5.0 mol % of a readily available monodentate phosphoram...

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Veröffentlicht in:	Angewandte Chemie International Edition 2020-08, Vol.59 (33), p.14070-14075
Hauptverfasser:	Marcum, Justin S., Taylor, Tiffany R., Meek, Simon J.
Format:	Artikel
Sprache:	eng
Schlagworte:	Aromatic compounds Boronates Chemical synthesis Dienes Enantiomers enantioselective Ethanol homogeneous catalysis hydroarylation Nickel
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