meso‐Diazacorrphycenes: Neighboring Effect of Two Nitrogen Atoms

The neighboring effect of two adjacent heteroatoms influences the structures and properties of heterocyclic compounds. Herein, we demonstrated that the introduction of two adjacent sp2 nitrogen atoms into a porphyrinic skeleton significantly enhanced its Brønsted basicity due to the repulsive intera...

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Veröffentlicht in:	Chemistry : a European journal 2020-07, Vol.26 (37), p.8210-8213
Hauptverfasser:	Yagi, Atsumi, Shinokubo, Hiroshi
Format:	Artikel
Sprache:	eng
Schlagworte:	aromaticity Basicity Chemistry Coordination compounds Copper Copper compounds Electrochemical analysis Electrochemistry Heterocyclic compounds Hydrazine Hydrazines Magnetic properties neighboring effect Nitrogen Nitrogen atoms Palladium porphyrinoid
Online-Zugang:	Volltext
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