Fundamental Studies of the Singlet Oxygen Reactions with the Potent Marine Toxin Domoic Acid

Domoic acid (DA), a potent marine toxin, is readily oxidized upon reaction with singlet oxygen (1O2). Detailed product studies revealed that the major singlet oxygenation reaction pathways were the [2 + 2] cycloaddition (60.2%) and ene reactions (39.8%) occurring at the Z double bond. Diene isomeriz...

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Veröffentlicht in:	Environmental science & technology 2020-05, Vol.54 (10), p.6073-6081
Hauptverfasser:	Jaramillo, Marcela, Joens, Jeffrey A, O’Shea, Kevin E
Format:	Artikel
Sprache:	eng
Schlagworte:	Biological activity Cycloaddition Detoxification Domoic acid Isomerization Natural waters Oxidation Oxygen Oxygenation Reaction kinetics Reaction products Risk assessment Singlet oxygen Surface water Toxins
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