An Arylazopyrazole‐Based N‐Heterocyclic Carbene as a Photoswitch on Gold Surfaces: Light‐Switchable Wettability, Work Function, and Conductance

A novel photoresponsive and fully conjugated N‐heterocyclic carbene (NHC) has been synthesized that combines the excellent photophysical properties of arylazopyrazoles (AAPs) with an NHC that acts as a robust surface anchor (AAP‐BIMe). The formation of self‐assembled monolayers (SAMs) on gold was pr...

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Veröffentlicht in:Angewandte Chemie International Edition 2020-08, Vol.59 (32), p.13651-13656
Hauptverfasser: Nguyen, D. Thao, Freitag, Matthias, Gutheil, Christian, Sotthewes, Kai, Tyler, Bonnie J., Böckmann, Marcus, Das, Mowpriya, Schlüter, Friederike, Doltsinis, Nikos L., Arlinghaus, Heinrich F., Ravoo, Bart Jan, Glorius, Frank
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Sprache:eng
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