Lithium Bonds in Lithium Batteries

Lithium bonds are analogous to hydrogen bonds and are therefore expected to exhibit similar characteristics and functions. Additionally, the metallic nature and large atomic radius of Li bestow the Li bond with special features. As one of the most important applications of the element, Li batteries...

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Veröffentlicht in:Angewandte Chemie International Edition 2020-07, Vol.59 (28), p.11192-11195
Hauptverfasser: Chen, Xiang, Bai, Yun‐Ke, Zhao, Chen‐Zi, Shen, Xin, Zhang, Qiang
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container_issue 28
container_start_page 11192
container_title Angewandte Chemie International Edition
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creator Chen, Xiang
Bai, Yun‐Ke
Zhao, Chen‐Zi
Shen, Xin
Zhang, Qiang
description Lithium bonds are analogous to hydrogen bonds and are therefore expected to exhibit similar characteristics and functions. Additionally, the metallic nature and large atomic radius of Li bestow the Li bond with special features. As one of the most important applications of the element, Li batteries afford emerging opportunities for the exploration of Li bond chemistry. Herein, the historical development and concept of the Li bond are reviewed, in addition to the application of Li bonds in Li batteries. In this way, a comprehensive understanding of the Li bond in Li batteries and an outlook on its future developments is presented. Lithium bonds that are present in lithium batteries are discussed in this Viewpoint, including historical developments, comparisons with hydrogen bonds, and their potential applications. Discourse on the chemistry of the Li bond can provide fruitful insight into the fundamental interactions within Li batteries and thus deliver a deeper understanding of their working mechanism.
doi_str_mv 10.1002/anie.201915623
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subjects Atomic radius
Batteries
Chemical bonds
Hydrogen bonding
Hydrogen bonds
Lithium
Lithium batteries
lithium bonds
title Lithium Bonds in Lithium Batteries
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