Sustainable Synthesis and Polycondensation of Levoglucosenone‐Cyrene‐Based Bicyclic Diol Monomer: Access to Renewable Polyesters

The already‐reported, low‐yielding, and non‐sustainable Et3N‐mediated homocoupling of levoglucosenone (LGO) into the corresponding LGO‐CyreneTM diketone has been revisited and greened‐up. The use of methanol as both a renewable solvent and catalyst and K2CO3 as a safe inorganic base improved the rea...

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Veröffentlicht in:	ChemSusChem 2020-05, Vol.13 (10), p.2613-2620
Hauptverfasser:	Diot‐Néant, Florian, Mouterde, Louis, Fadlallah, Sami, Miller, Stephen A., Allais, Florent
Format:	Artikel
Sprache:	eng
Schlagworte:	Acidic oxides biomass Bulk polymerization Diketones dimerization Glass transition temperature Hydrogen peroxide Monomers Oxidation Polyester resins Polyesters polymers Potassium carbonate synthesis design Thermal stability
Online-Zugang:	Volltext
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