Solid-State Spin Equilibrium of Ni(cyclam)2 Complex: Magnetostructural Correlations in Two Polymorphs

Two crystal polymorphs of Ni­(cyclam)­I2 (cyclam = 1,4,8,11-tetraazacyclotetradecane) were synthesized, and their magnetic properties were investigated. Temperature-dependent X-ray structural analysis and magnetic measurements revealed gradual spin transition in molecular-crystal polymorph trans-[Ni...

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Veröffentlicht in:Inorganic chemistry 2020-04, Vol.59 (8), p.5418-5423
Hauptverfasser: Horii, Yoji, Kanegae, Yuki, Takahashi, Kiyonori, Fuyuhiro, Akira, Noguchi, Mariko, Suzuki, Hal, Nakano, Motohiro
Format: Artikel
Sprache:eng
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