Aqueous Palladium‐Catalyzed Direct Arylation Polymerization of 2‐Bromothiophene Derivatives

Aqueous palladium‐catalyzed direct arylation polymerization (DArP) of 2‐bromothiophene derivatives 6‐(2‐(2‐bromothiophen‐3‐yl)ethoxy)hexyl trimethylammonium bromide (T1) and 4‐(2‐(2‐bromothien‐3‐yl)ethoxy)butylsulfonate (T2) is achieved. The supporting ligand, triphenylphosphine‐3,3′,3′′‐trisulfonic...

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Veröffentlicht in:	Macromolecular rapid communications. 2020-05, Vol.41 (9), p.e2000021-n/a
Hauptverfasser:	Lin, Yu‐Jen, Sun, Han‐Sheng, Yang, Hau‐Ren, Lai, Yu‐Ying, Hou, Kai‐Yuan, Liu, Yi‐Hung
Format:	Artikel
Sprache:	eng
Schlagworte:	Agglomeration aggregation effect aqueous polymerization Catalysis conjugated polymers Contamination Crystallography Density functional theory Derivatives Dialysis direct arylation Ligands Light scattering Liquid chromatography Molecular Structure Molecular weight Palladium Palladium - chemistry Photon correlation spectroscopy Polyelectrolytes Polymerization Polymers Sulfonic Acids - chemistry Trimethyl Ammonium Compounds - chemistry Water - chemistry
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