Fluoroalkanesulfinate Salts as Dual Fluoroalkyl and SO2 Sources: Atom-Economical Fluoroalkyl-Sulfonylation of Alkenes and Alkynes by Photoredox Catalysis

We disclose that fluoroalkanesulfinate salts ((RFSO2) n M) such as the Langlois reagent, CF3SO2Na, serve as dual fluoroalkyl (RF) and sulfur dioxide (SO2) sources by the action of photoredox catalysis. An operationally simple strategy for the vicinal installation of RF and SO2 groups onto unsaturate...

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Veröffentlicht in:	Organic letters 2020-04, Vol.22 (7), p.2801-2805
Hauptverfasser:	Tanaka, Seiya, Nakayama, Yoshiki, Konishi, Yusuke, Koike, Takashi, Akita, Munetaka
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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