Low power consumption and fast response H2S gas sensor based on a chitosan-CuO hybrid nanocomposite thin film
•Chitosan-CuO-IL flexible membrane were successfully prepared for H2S gas detection at 40 °C.•CS-CuO-IL membrane is inexpensive to make, environmentally friendly, and energy-efficient.•The fabricated sensor is selective, sensitive and having fast response time of 14 s.•The sensor is having long-term...
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Veröffentlicht in: | Carbohydrate polymers 2020-05, Vol.236, p.116064-116064, Article 116064 |
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creator | Ali, Fajr I.M. Mahmoud, Saleh T. Awwad, Falah Greish, Yaser E. Abu-Hani, Ayah F.S. |
description | •Chitosan-CuO-IL flexible membrane were successfully prepared for H2S gas detection at 40 °C.•CS-CuO-IL membrane is inexpensive to make, environmentally friendly, and energy-efficient.•The fabricated sensor is selective, sensitive and having fast response time of 14 s.•The sensor is having long-term stability and low power consumption.
In this work, a novel selective and low temperature H2S gas sensor was fabricated based on copper (II) oxide nanoparticles (CuO NPs) in different concentrations, embedded in a conductivity-engineered organic (glycerol ionic liquid-doped chitosan) membrane/film. The sensing membranes of organic-inorganic nanocomposites (CS-IL-CuO) were prepared by casting method and were tested against H2S gas with reference to time at different temperatures and H2S gas concentrations. The fabricated sensor showed a fast response (14 s) and good sensitivity (15 ppm) towards H2S gas at a low temperature of 40 °C. Moreover, the sensor showed a high reversibility and less humidity dependence at 40 °C. Moreover, this type of hybrid nanocomposites sensor is easy and inexpensive to manufacture and is energy efficient. Thus, it has potential to be used for industrial applications in harsh environments. |
doi_str_mv | 10.1016/j.carbpol.2020.116064 |
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In this work, a novel selective and low temperature H2S gas sensor was fabricated based on copper (II) oxide nanoparticles (CuO NPs) in different concentrations, embedded in a conductivity-engineered organic (glycerol ionic liquid-doped chitosan) membrane/film. The sensing membranes of organic-inorganic nanocomposites (CS-IL-CuO) were prepared by casting method and were tested against H2S gas with reference to time at different temperatures and H2S gas concentrations. The fabricated sensor showed a fast response (14 s) and good sensitivity (15 ppm) towards H2S gas at a low temperature of 40 °C. Moreover, the sensor showed a high reversibility and less humidity dependence at 40 °C. Moreover, this type of hybrid nanocomposites sensor is easy and inexpensive to manufacture and is energy efficient. Thus, it has potential to be used for industrial applications in harsh environments.</description><identifier>ISSN: 0144-8617</identifier><identifier>EISSN: 1879-1344</identifier><identifier>DOI: 10.1016/j.carbpol.2020.116064</identifier><language>eng</language><publisher>Elsevier Ltd</publisher><subject>Chitosan ; CuO nanoparticles ; H2S sensor ; Ionic liquid ; Organic-inorganic nanocomposite ; Semiconductor polymer ; Sensor response time ; Sensor-based methods ; Toxic gas</subject><ispartof>Carbohydrate polymers, 2020-05, Vol.236, p.116064-116064, Article 116064</ispartof><rights>2020 Elsevier Ltd</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c342t-3ac069445a165c8cd3fa5c77f6e8c1511ea7a281e0108b9ba8323cc076f74ee33</citedby><cites>FETCH-LOGICAL-c342t-3ac069445a165c8cd3fa5c77f6e8c1511ea7a281e0108b9ba8323cc076f74ee33</cites><orcidid>0000-0002-7147-6773</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.carbpol.2020.116064$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3550,27924,27925,45995</link.rule.ids></links><search><creatorcontrib>Ali, Fajr I.M.</creatorcontrib><creatorcontrib>Mahmoud, Saleh T.</creatorcontrib><creatorcontrib>Awwad, Falah</creatorcontrib><creatorcontrib>Greish, Yaser E.</creatorcontrib><creatorcontrib>Abu-Hani, Ayah F.S.</creatorcontrib><title>Low power consumption and fast response H2S gas sensor based on a chitosan-CuO hybrid nanocomposite thin film</title><title>Carbohydrate polymers</title><description>•Chitosan-CuO-IL flexible membrane were successfully prepared for H2S gas detection at 40 °C.•CS-CuO-IL membrane is inexpensive to make, environmentally friendly, and energy-efficient.•The fabricated sensor is selective, sensitive and having fast response time of 14 s.•The sensor is having long-term stability and low power consumption.
In this work, a novel selective and low temperature H2S gas sensor was fabricated based on copper (II) oxide nanoparticles (CuO NPs) in different concentrations, embedded in a conductivity-engineered organic (glycerol ionic liquid-doped chitosan) membrane/film. The sensing membranes of organic-inorganic nanocomposites (CS-IL-CuO) were prepared by casting method and were tested against H2S gas with reference to time at different temperatures and H2S gas concentrations. The fabricated sensor showed a fast response (14 s) and good sensitivity (15 ppm) towards H2S gas at a low temperature of 40 °C. Moreover, the sensor showed a high reversibility and less humidity dependence at 40 °C. Moreover, this type of hybrid nanocomposites sensor is easy and inexpensive to manufacture and is energy efficient. Thus, it has potential to be used for industrial applications in harsh environments.</description><subject>Chitosan</subject><subject>CuO nanoparticles</subject><subject>H2S sensor</subject><subject>Ionic liquid</subject><subject>Organic-inorganic nanocomposite</subject><subject>Semiconductor polymer</subject><subject>Sensor response time</subject><subject>Sensor-based methods</subject><subject>Toxic gas</subject><issn>0144-8617</issn><issn>1879-1344</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNqFkE9r4zAQxUXZQrPdfoSCjntxKlmy5JxKCf0HgRx29yzk8bhRsCWvxmnpt69Dcu9cHjzeezA_xm6lWEohzd1-CT43Y-qXpShnTxph9AVbyNquCqm0_sEWQmpd1EbaK_aTaC_mM1Is2LBJH3xMH5g5pEiHYZxCitzHlneeJp6RxtlH_lL-4W-eOGGklHnjCVt-THLYhSmRj8X6sOW7zyaHlkcfE6RhTBQm5NMuRN6FfvjFLjvfE96c9Zr9e3r8u34pNtvn1_XDpgCly6lQHoRZaV15aSqooVWdr8DazmANspISvfVlLVFIUTerxteqVADCms5qRKWu2e_T7pjT_wPS5IZAgH3vI6YDuVJZa2pttJ2j1SkKORFl7NyYw-Dzp5PCHfG6vTvjdUe87oR37t2fejj_8R4wO4KAEbANGWFybQrfLHwBtuKG2g</recordid><startdate>20200515</startdate><enddate>20200515</enddate><creator>Ali, Fajr I.M.</creator><creator>Mahmoud, Saleh T.</creator><creator>Awwad, Falah</creator><creator>Greish, Yaser E.</creator><creator>Abu-Hani, Ayah F.S.</creator><general>Elsevier Ltd</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0002-7147-6773</orcidid></search><sort><creationdate>20200515</creationdate><title>Low power consumption and fast response H2S gas sensor based on a chitosan-CuO hybrid nanocomposite thin film</title><author>Ali, Fajr I.M. ; Mahmoud, Saleh T. ; Awwad, Falah ; Greish, Yaser E. ; Abu-Hani, Ayah F.S.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c342t-3ac069445a165c8cd3fa5c77f6e8c1511ea7a281e0108b9ba8323cc076f74ee33</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Chitosan</topic><topic>CuO nanoparticles</topic><topic>H2S sensor</topic><topic>Ionic liquid</topic><topic>Organic-inorganic nanocomposite</topic><topic>Semiconductor polymer</topic><topic>Sensor response time</topic><topic>Sensor-based methods</topic><topic>Toxic gas</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ali, Fajr I.M.</creatorcontrib><creatorcontrib>Mahmoud, Saleh T.</creatorcontrib><creatorcontrib>Awwad, Falah</creatorcontrib><creatorcontrib>Greish, Yaser E.</creatorcontrib><creatorcontrib>Abu-Hani, Ayah F.S.</creatorcontrib><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Carbohydrate polymers</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ali, Fajr I.M.</au><au>Mahmoud, Saleh T.</au><au>Awwad, Falah</au><au>Greish, Yaser E.</au><au>Abu-Hani, Ayah F.S.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Low power consumption and fast response H2S gas sensor based on a chitosan-CuO hybrid nanocomposite thin film</atitle><jtitle>Carbohydrate polymers</jtitle><date>2020-05-15</date><risdate>2020</risdate><volume>236</volume><spage>116064</spage><epage>116064</epage><pages>116064-116064</pages><artnum>116064</artnum><issn>0144-8617</issn><eissn>1879-1344</eissn><abstract>•Chitosan-CuO-IL flexible membrane were successfully prepared for H2S gas detection at 40 °C.•CS-CuO-IL membrane is inexpensive to make, environmentally friendly, and energy-efficient.•The fabricated sensor is selective, sensitive and having fast response time of 14 s.•The sensor is having long-term stability and low power consumption.
In this work, a novel selective and low temperature H2S gas sensor was fabricated based on copper (II) oxide nanoparticles (CuO NPs) in different concentrations, embedded in a conductivity-engineered organic (glycerol ionic liquid-doped chitosan) membrane/film. The sensing membranes of organic-inorganic nanocomposites (CS-IL-CuO) were prepared by casting method and were tested against H2S gas with reference to time at different temperatures and H2S gas concentrations. The fabricated sensor showed a fast response (14 s) and good sensitivity (15 ppm) towards H2S gas at a low temperature of 40 °C. Moreover, the sensor showed a high reversibility and less humidity dependence at 40 °C. Moreover, this type of hybrid nanocomposites sensor is easy and inexpensive to manufacture and is energy efficient. Thus, it has potential to be used for industrial applications in harsh environments.</abstract><pub>Elsevier Ltd</pub><doi>10.1016/j.carbpol.2020.116064</doi><tpages>1</tpages><orcidid>https://orcid.org/0000-0002-7147-6773</orcidid></addata></record> |
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subjects | Chitosan CuO nanoparticles H2S sensor Ionic liquid Organic-inorganic nanocomposite Semiconductor polymer Sensor response time Sensor-based methods Toxic gas |
title | Low power consumption and fast response H2S gas sensor based on a chitosan-CuO hybrid nanocomposite thin film |
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