High-Pressure Synthesis of Two Polymorphic HgMnO3 Phases and Distinct Magnetism from 2D to 3D

An ilmenite-like monoclinic phase of HgMnO3 with space group P21/c was prepared using high-pressure and high-temperature methods at 18 GPa and 1473 K. The MnO6 octahedra form a two-dimensional (2D) network in the bc plane, leading to a long-range antiferromagnetic ordering with a low Néel temperatu...

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Veröffentlicht in:Inorganic chemistry 2020-03, Vol.59 (6), p.3887-3893
Hauptverfasser: Zhou, Bowen, Qin, Shijun, Ma, Teng, Ye, Xubin, Guo, Jia, Yu, Xiaohui, Lin, Hong-Ji, Chen, Chien-Te, Hu, Zhiwei, Tjeng, Liu-Hao, Zhou, Guanghui, Dong, Cheng, Long, Youwen
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Sprache:eng
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