Effects of Mixed Valency in an Fe-Based Framework: Coexistence of Slow Magnetic Relaxation, Semiconductivity, and Redox Activity

A 2-D coordination framework, (NEt4)2[Fe2(fan)3] (1·5­(acetone); H2fan = 3,6-difluoro-2,5-dihydroxy-1,4-benzoquinone), was synthesized and structurally characterized. The compound is structurally analogous to a formerly elucidated framework, (NEt4)2[Fe2(can)3] (H2can = 3,6-dichloro-2,5-dihydroxy-1,4...

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Veröffentlicht in:	Inorganic chemistry 2020-03, Vol.59 (6), p.3619-3630
Hauptverfasser:	Murase, Ryuichi, Commons, Christopher J, Hudson, Timothy A, Jameson, Guy N. L, Ling, Chris D, Murray, Keith S, Phonsri, Wasinee, Robson, Richard, Xia, Qingbo, Abrahams, Brendan F, D’Alessandro, Deanna M
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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