Aminoalkyl radicals as halogen-atom transfer agents for activation of alkyl and aryl halides

Organic halides are important building blocks in synthesis, but their use in (photo)redox chemistry is limited by their low reduction potentials. Halogen-atom transfer remains the most reliable approach to exploit these substrates in radical processes despite its requirement for hazardous reagents a...

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Veröffentlicht in:Science (American Association for the Advancement of Science) 2020-02, Vol.367 (6481), p.1021-1026
Hauptverfasser: Constantin, Timothée, Zanini, Margherita, Regni, Alessio, Sheikh, Nadeem S, Juliá, Fabio, Leonori, Daniele
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Sprache:eng
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