Extraction of metallic cations by anodically formed poly-dibenzo-18-crown-6 from aqueous solutions. A key step in the formation of metal-polymer materials used as electrode modifiers for electrocatalysis

Extraction of metallic cations by anodically formed poly-dibenzo-18-crown-6 from aqueous solutions. A key step in the formation of metal-polymer materials used as electrode modifiers for electrocatalysis

The insertion of metallic particles (Pd, Pt, Ir, Rh, Au or Ag) in conductive poly-crown-ether polymers such as poly-dibenzo-18-crown-6 (poly-DB18-C6, a polymer synthesized by anodic means) is described. The electrochemical behaviours of the metal-polymer materials are presented and the catalytic act...

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Veröffentlicht in:Synthetic metals 1992-01, Vol.52 (3), p.273-289
Hauptverfasser: Angely, L, Rault-Berthelot, J, Peslerbe, G
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container_title Synthetic metals
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creator Angely, L
Rault-Berthelot, J
Peslerbe, G
description The insertion of metallic particles (Pd, Pt, Ir, Rh, Au or Ag) in conductive poly-crown-ether polymers such as poly-dibenzo-18-crown-6 (poly-DB18-C6, a polymer synthesized by anodic means) is described. The electrochemical behaviours of the metal-polymer materials are presented and the catalytic activity of the platinum-polymer is tested with regard to hydrogen evolution or formic acid oxidation in acidic solutions. Finally, an X-ray diffraction scattering study depicts the crystallographic patterns of the metal-polymer samples.
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title Extraction of metallic cations by anodically formed poly-dibenzo-18-crown-6 from aqueous solutions. A key step in the formation of metal-polymer materials used as electrode modifiers for electrocatalysis
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