Potential of Carboxymethylated Polyallylamine as a Functional Group on Chelating Resin for Solid-Phase Extraction of Trace Elements
New chelating resins immobilizing carboxymethylated polyallylamine (CM-PAA) were prepared by immobilizing PAAs with some molecular weights on methacrylate resins and then carboxymethylating a part of amino groups in the PAAs using various amounts of sodium monochloroacetate. The molecular weight of...
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| Veröffentlicht in: | Analytical Sciences 2020/05/10, Vol.36(5), pp.583-588 |
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| creator | KAGAYA, Shigehiro SAEKI, Yumi MORISHIMA, Daiki KAJIWARA, Takehiro KAMICHATANI, Waka YANAI, Hideyuki KATOH, Toshifumi SAITO, Mitsuru GEMMEI-IDE, Makoto INOUE, Yoshinori |
| description | New chelating resins immobilizing carboxymethylated polyallylamine (CM-PAA) were prepared by immobilizing PAAs with some molecular weights on methacrylate resins and then carboxymethylating a part of amino groups in the PAAs using various amounts of sodium monochloroacetate. The molecular weight of PAA barely affected both the amount of PAA immobilized on the resin and the relationship between the carboxymethylation (CM) rate and the ratio of the amount of monochloroacetate used in the CM step. The selectivity of CM-PAA resin for solid-phase extraction of trace elements was almost the same as that of a resin immobilizing carboxylymethylated polyethyleneimine; 10 elements, namely Cd, Co, Cu, Fe, Mo, Ni, Pb, Ti, V, and Zn, could be quantitatively recovered over a wide pH range and alkali and alkaline earth elements were scarcely extracted under acidic and neutral conditions. The CM-PAA resin was applicable to the separation and preconcentration of the elements in a certified reference material (Waste Water, EU-L-1) and a real environmental water sample (ground water). |
| doi_str_mv | 10.2116/analsci.19SBP10 |
| format | Article |
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The molecular weight of PAA barely affected both the amount of PAA immobilized on the resin and the relationship between the carboxymethylation (CM) rate and the ratio of the amount of monochloroacetate used in the CM step. The selectivity of CM-PAA resin for solid-phase extraction of trace elements was almost the same as that of a resin immobilizing carboxylymethylated polyethyleneimine; 10 elements, namely Cd, Co, Cu, Fe, Mo, Ni, Pb, Ti, V, and Zn, could be quantitatively recovered over a wide pH range and alkali and alkaline earth elements were scarcely extracted under acidic and neutral conditions. The CM-PAA resin was applicable to the separation and preconcentration of the elements in a certified reference material (Waste Water, EU-L-1) and a real environmental water sample (ground water).</description><identifier>ISSN: 0910-6340</identifier><identifier>EISSN: 1348-2246</identifier><identifier>DOI: 10.2116/analsci.19SBP10</identifier><identifier>PMID: 32092733</identifier><language>eng</language><publisher>Singapore: The Japan Society for Analytical Chemistry</publisher><subject>Acrylic resins ; Amino groups ; Analytical Chemistry ; Cadmium ; Carboxymethylation ; Chelating resin immobilizing carboxymethylated polyallylamine ; Chelating resins ; Chelation ; Chemistry ; Copper ; environmental water sample ; Functional groups ; Groundwater ; Immobilization ; Lead ; Molecular weight ; Molybdenum ; Nickel ; Polyallylamine ; Polyethyleneimine ; Polymers ; Resins ; Selectivity ; Solid phases ; solid-phase extraction ; Titanium ; trace element ; Trace elements ; Wastewater ; Water analysis ; Water sampling</subject><ispartof>Analytical Sciences, 2020/05/10, Vol.36(5), pp.583-588</ispartof><rights>2020 by The Japan Society for Analytical Chemistry</rights><rights>The Japan Society for Analytical Chemistry 2020</rights><rights>Copyright Japan Science and Technology Agency 2020</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c663t-629be454c201060000d4095453739b99e04a3fd5e335b567171d1c7ed5cc5bb13</citedby><cites>FETCH-LOGICAL-c663t-629be454c201060000d4095453739b99e04a3fd5e335b567171d1c7ed5cc5bb13</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.2116/analsci.19SBP10$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.2116/analsci.19SBP10$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,1883,27924,27925,41488,42557,51319</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/32092733$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>KAGAYA, Shigehiro</creatorcontrib><creatorcontrib>SAEKI, Yumi</creatorcontrib><creatorcontrib>MORISHIMA, Daiki</creatorcontrib><creatorcontrib>KAJIWARA, Takehiro</creatorcontrib><creatorcontrib>KAMICHATANI, Waka</creatorcontrib><creatorcontrib>YANAI, Hideyuki</creatorcontrib><creatorcontrib>KATOH, Toshifumi</creatorcontrib><creatorcontrib>SAITO, Mitsuru</creatorcontrib><creatorcontrib>GEMMEI-IDE, Makoto</creatorcontrib><creatorcontrib>INOUE, Yoshinori</creatorcontrib><title>Potential of Carboxymethylated Polyallylamine as a Functional Group on Chelating Resin for Solid-Phase Extraction of Trace Elements</title><title>Analytical Sciences</title><addtitle>ANAL. SCI</addtitle><addtitle>Anal Sci</addtitle><description>New chelating resins immobilizing carboxymethylated polyallylamine (CM-PAA) were prepared by immobilizing PAAs with some molecular weights on methacrylate resins and then carboxymethylating a part of amino groups in the PAAs using various amounts of sodium monochloroacetate. The molecular weight of PAA barely affected both the amount of PAA immobilized on the resin and the relationship between the carboxymethylation (CM) rate and the ratio of the amount of monochloroacetate used in the CM step. The selectivity of CM-PAA resin for solid-phase extraction of trace elements was almost the same as that of a resin immobilizing carboxylymethylated polyethyleneimine; 10 elements, namely Cd, Co, Cu, Fe, Mo, Ni, Pb, Ti, V, and Zn, could be quantitatively recovered over a wide pH range and alkali and alkaline earth elements were scarcely extracted under acidic and neutral conditions. 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SAEKI, Yumi ; MORISHIMA, Daiki ; KAJIWARA, Takehiro ; KAMICHATANI, Waka ; YANAI, Hideyuki ; KATOH, Toshifumi ; SAITO, Mitsuru ; GEMMEI-IDE, Makoto ; INOUE, Yoshinori</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c663t-629be454c201060000d4095453739b99e04a3fd5e335b567171d1c7ed5cc5bb13</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Acrylic resins</topic><topic>Amino groups</topic><topic>Analytical Chemistry</topic><topic>Cadmium</topic><topic>Carboxymethylation</topic><topic>Chelating resin immobilizing carboxymethylated polyallylamine</topic><topic>Chelating resins</topic><topic>Chelation</topic><topic>Chemistry</topic><topic>Copper</topic><topic>environmental water sample</topic><topic>Functional groups</topic><topic>Groundwater</topic><topic>Immobilization</topic><topic>Lead</topic><topic>Molecular weight</topic><topic>Molybdenum</topic><topic>Nickel</topic><topic>Polyallylamine</topic><topic>Polyethyleneimine</topic><topic>Polymers</topic><topic>Resins</topic><topic>Selectivity</topic><topic>Solid phases</topic><topic>solid-phase extraction</topic><topic>Titanium</topic><topic>trace element</topic><topic>Trace elements</topic><topic>Wastewater</topic><topic>Water analysis</topic><topic>Water sampling</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>KAGAYA, Shigehiro</creatorcontrib><creatorcontrib>SAEKI, Yumi</creatorcontrib><creatorcontrib>MORISHIMA, Daiki</creatorcontrib><creatorcontrib>KAJIWARA, Takehiro</creatorcontrib><creatorcontrib>KAMICHATANI, Waka</creatorcontrib><creatorcontrib>YANAI, Hideyuki</creatorcontrib><creatorcontrib>KATOH, Toshifumi</creatorcontrib><creatorcontrib>SAITO, Mitsuru</creatorcontrib><creatorcontrib>GEMMEI-IDE, Makoto</creatorcontrib><creatorcontrib>INOUE, Yoshinori</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Aluminium Industry Abstracts</collection><collection>Biotechnology Research Abstracts</collection><collection>Ceramic Abstracts</collection><collection>Corrosion Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Engineering Research Database</collection><collection>Copper Technical Reference Library</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Biotechnology and BioEngineering Abstracts</collection><collection>MEDLINE - Academic</collection><jtitle>Analytical Sciences</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>KAGAYA, Shigehiro</au><au>SAEKI, Yumi</au><au>MORISHIMA, Daiki</au><au>KAJIWARA, Takehiro</au><au>KAMICHATANI, Waka</au><au>YANAI, Hideyuki</au><au>KATOH, Toshifumi</au><au>SAITO, Mitsuru</au><au>GEMMEI-IDE, Makoto</au><au>INOUE, Yoshinori</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Potential of Carboxymethylated Polyallylamine as a Functional Group on Chelating Resin for Solid-Phase Extraction of Trace Elements</atitle><jtitle>Analytical Sciences</jtitle><stitle>ANAL. SCI</stitle><addtitle>Anal Sci</addtitle><date>2020-05-10</date><risdate>2020</risdate><volume>36</volume><issue>5</issue><spage>583</spage><epage>588</epage><pages>583-588</pages><issn>0910-6340</issn><eissn>1348-2246</eissn><abstract>New chelating resins immobilizing carboxymethylated polyallylamine (CM-PAA) were prepared by immobilizing PAAs with some molecular weights on methacrylate resins and then carboxymethylating a part of amino groups in the PAAs using various amounts of sodium monochloroacetate. The molecular weight of PAA barely affected both the amount of PAA immobilized on the resin and the relationship between the carboxymethylation (CM) rate and the ratio of the amount of monochloroacetate used in the CM step. The selectivity of CM-PAA resin for solid-phase extraction of trace elements was almost the same as that of a resin immobilizing carboxylymethylated polyethyleneimine; 10 elements, namely Cd, Co, Cu, Fe, Mo, Ni, Pb, Ti, V, and Zn, could be quantitatively recovered over a wide pH range and alkali and alkaline earth elements were scarcely extracted under acidic and neutral conditions. The CM-PAA resin was applicable to the separation and preconcentration of the elements in a certified reference material (Waste Water, EU-L-1) and a real environmental water sample (ground water).</abstract><cop>Singapore</cop><pub>The Japan Society for Analytical Chemistry</pub><pmid>32092733</pmid><doi>10.2116/analsci.19SBP10</doi><tpages>6</tpages><oa>free_for_read</oa></addata></record> |
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| subjects | Acrylic resins Amino groups Analytical Chemistry Cadmium Carboxymethylation Chelating resin immobilizing carboxymethylated polyallylamine Chelating resins Chelation Chemistry Copper environmental water sample Functional groups Groundwater Immobilization Lead Molecular weight Molybdenum Nickel Polyallylamine Polyethyleneimine Polymers Resins Selectivity Solid phases solid-phase extraction Titanium trace element Trace elements Wastewater Water analysis Water sampling |
| title | Potential of Carboxymethylated Polyallylamine as a Functional Group on Chelating Resin for Solid-Phase Extraction of Trace Elements |
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