Facilitate Gas Transport through Metal‐Organic Polyhedra Constructed Porous Liquid Membrane
Type II porous liquids are demonstrated to be promise porous materials. However, the category of porous hosts is very limited. Here, a porous host metal–organic polyhedra (MOP‐18) is reported to construct type II porous liquids. MOP‐18 is dissolved into 15‐crown‐5 as an individual cage (5 nm). Both...
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| Veröffentlicht in: | Small (Weinheim an der Bergstrasse, Germany) Germany), 2020-03, Vol.16 (11), p.e1907016-n/a |
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| creator | Deng, Zheng Ying, Wen Gong, Ke Zeng, Yu‐Jia Yan, Youguo Peng, Xinsheng |
| description | Type II porous liquids are demonstrated to be promise porous materials. However, the category of porous hosts is very limited. Here, a porous host metal–organic polyhedra (MOP‐18) is reported to construct type II porous liquids. MOP‐18 is dissolved into 15‐crown‐5 as an individual cage (5 nm). Both the molecular dynamics simulations and experimental gravimetric CO2 solubility test indicate that the inner cavity of MOP‐18 in porous liquids is unoccupied by 15‐crown‐5 and is accessible to CO2. Thus, the prepared porous liquids show enhanced gas solubility. Furthermore, the prepared porous liquid is encapsulated into graphene oxide (GO) nanoslits to form a GO‐supported porous liquid membrane (GO‐SPLM). Owing to the empty cavity of MOP‐18 unit cages in porous liquids that reduces the gas diffusion barrier, GO‐SPLM significantly enhances the permeability of gas.
A type II porous liquid is constructed by using MOP‐18 and 15‐crown‐5 as the porous host and bulky solvent, respectively. The existence of permanent porosity in porous liquid is confirmed by both the molecular dynamics simulations and experimental date. The unoccupied cavity in the porous liquid can be used for gas storage and facilitating the gas transportation. |
| doi_str_mv | 10.1002/smll.201907016 |
| format | Article |
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A type II porous liquid is constructed by using MOP‐18 and 15‐crown‐5 as the porous host and bulky solvent, respectively. The existence of permanent porosity in porous liquid is confirmed by both the molecular dynamics simulations and experimental date. The unoccupied cavity in the porous liquid can be used for gas storage and facilitating the gas transportation.</description><identifier>ISSN: 1613-6810</identifier><identifier>EISSN: 1613-6829</identifier><identifier>DOI: 10.1002/smll.201907016</identifier><identifier>PMID: 32083785</identifier><language>eng</language><publisher>Germany: Wiley Subscription Services, Inc</publisher><subject>Carbon dioxide ; Diffusion barriers ; Gas solubility ; Gas transport ; gas transportation ; Gaseous diffusion ; Graphene ; Gravimetry ; liquid membrane ; Liquid membranes ; Liquids ; metal–organic polyhedra ; Molecular dynamics ; MOP‐18 ; Nanotechnology ; Polyhedra ; porous liquid ; Porous materials ; type II porous liquids</subject><ispartof>Small (Weinheim an der Bergstrasse, Germany), 2020-03, Vol.16 (11), p.e1907016-n/a</ispartof><rights>2020 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>2020 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4106-83b0734e1b85a0661a8375875843e71ef9f71f6cc57505da2b4c7c7729aa9bce3</citedby><cites>FETCH-LOGICAL-c4106-83b0734e1b85a0661a8375875843e71ef9f71f6cc57505da2b4c7c7729aa9bce3</cites><orcidid>0000-0002-5355-4854</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fsmll.201907016$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fsmll.201907016$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27901,27902,45550,45551</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/32083785$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Deng, Zheng</creatorcontrib><creatorcontrib>Ying, Wen</creatorcontrib><creatorcontrib>Gong, Ke</creatorcontrib><creatorcontrib>Zeng, Yu‐Jia</creatorcontrib><creatorcontrib>Yan, Youguo</creatorcontrib><creatorcontrib>Peng, Xinsheng</creatorcontrib><title>Facilitate Gas Transport through Metal‐Organic Polyhedra Constructed Porous Liquid Membrane</title><title>Small (Weinheim an der Bergstrasse, Germany)</title><addtitle>Small</addtitle><description>Type II porous liquids are demonstrated to be promise porous materials. However, the category of porous hosts is very limited. Here, a porous host metal–organic polyhedra (MOP‐18) is reported to construct type II porous liquids. MOP‐18 is dissolved into 15‐crown‐5 as an individual cage (5 nm). Both the molecular dynamics simulations and experimental gravimetric CO2 solubility test indicate that the inner cavity of MOP‐18 in porous liquids is unoccupied by 15‐crown‐5 and is accessible to CO2. Thus, the prepared porous liquids show enhanced gas solubility. Furthermore, the prepared porous liquid is encapsulated into graphene oxide (GO) nanoslits to form a GO‐supported porous liquid membrane (GO‐SPLM). Owing to the empty cavity of MOP‐18 unit cages in porous liquids that reduces the gas diffusion barrier, GO‐SPLM significantly enhances the permeability of gas.
A type II porous liquid is constructed by using MOP‐18 and 15‐crown‐5 as the porous host and bulky solvent, respectively. The existence of permanent porosity in porous liquid is confirmed by both the molecular dynamics simulations and experimental date. The unoccupied cavity in the porous liquid can be used for gas storage and facilitating the gas transportation.</description><subject>Carbon dioxide</subject><subject>Diffusion barriers</subject><subject>Gas solubility</subject><subject>Gas transport</subject><subject>gas transportation</subject><subject>Gaseous diffusion</subject><subject>Graphene</subject><subject>Gravimetry</subject><subject>liquid membrane</subject><subject>Liquid membranes</subject><subject>Liquids</subject><subject>metal–organic polyhedra</subject><subject>Molecular dynamics</subject><subject>MOP‐18</subject><subject>Nanotechnology</subject><subject>Polyhedra</subject><subject>porous liquid</subject><subject>Porous materials</subject><subject>type II porous liquids</subject><issn>1613-6810</issn><issn>1613-6829</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNqFkE1LwzAYx4Mobr5cPUrBi5fOvLRJe5ThptAxwXmUkqbplpG2W5Iiu_kR_Ix-EjM2J3gRHshD-D1__vwAuEJwgCDEd7bWeoAhSiGDiB6BPqKIhDTB6fFhR7AHzqxdQkgQjtgp6BEME8KSuA_eRlworRx3MhhzG8wMb-yqNS5wC9N280UwkY7rr4_PqZnzRongudWbhSwND4ZtY53phJOl__W0DTK17lTpb-rCB8kLcFJxbeXl_j0Hr6OH2fAxzKbjp-F9FooIQRompICMRBIVScwhpYj7dnHiJyKSIVmlFUMVFSJmMYxLjotIMMEYTjlPCyHJObjd5a5Mu-6kdXmtrJBa-w6-Vo4JxV4QialHb_6gy7YzjW_nKZawiGGIPTXYUcK01hpZ5Sujam42OYL5Vny-FZ8fxPuD631sV9SyPOA_pj2Q7oB3peXmn7j8ZZJlv-HfmCqQLg</recordid><startdate>20200301</startdate><enddate>20200301</enddate><creator>Deng, Zheng</creator><creator>Ying, Wen</creator><creator>Gong, Ke</creator><creator>Zeng, Yu‐Jia</creator><creator>Yan, Youguo</creator><creator>Peng, Xinsheng</creator><general>Wiley Subscription Services, Inc</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0002-5355-4854</orcidid></search><sort><creationdate>20200301</creationdate><title>Facilitate Gas Transport through Metal‐Organic Polyhedra Constructed Porous Liquid Membrane</title><author>Deng, Zheng ; Ying, Wen ; Gong, Ke ; Zeng, Yu‐Jia ; Yan, Youguo ; Peng, Xinsheng</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4106-83b0734e1b85a0661a8375875843e71ef9f71f6cc57505da2b4c7c7729aa9bce3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Carbon dioxide</topic><topic>Diffusion barriers</topic><topic>Gas solubility</topic><topic>Gas transport</topic><topic>gas transportation</topic><topic>Gaseous diffusion</topic><topic>Graphene</topic><topic>Gravimetry</topic><topic>liquid membrane</topic><topic>Liquid membranes</topic><topic>Liquids</topic><topic>metal–organic polyhedra</topic><topic>Molecular dynamics</topic><topic>MOP‐18</topic><topic>Nanotechnology</topic><topic>Polyhedra</topic><topic>porous liquid</topic><topic>Porous materials</topic><topic>type II porous liquids</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Deng, Zheng</creatorcontrib><creatorcontrib>Ying, Wen</creatorcontrib><creatorcontrib>Gong, Ke</creatorcontrib><creatorcontrib>Zeng, Yu‐Jia</creatorcontrib><creatorcontrib>Yan, Youguo</creatorcontrib><creatorcontrib>Peng, Xinsheng</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Small (Weinheim an der Bergstrasse, Germany)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Deng, Zheng</au><au>Ying, Wen</au><au>Gong, Ke</au><au>Zeng, Yu‐Jia</au><au>Yan, Youguo</au><au>Peng, Xinsheng</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Facilitate Gas Transport through Metal‐Organic Polyhedra Constructed Porous Liquid Membrane</atitle><jtitle>Small (Weinheim an der Bergstrasse, Germany)</jtitle><addtitle>Small</addtitle><date>2020-03-01</date><risdate>2020</risdate><volume>16</volume><issue>11</issue><spage>e1907016</spage><epage>n/a</epage><pages>e1907016-n/a</pages><issn>1613-6810</issn><eissn>1613-6829</eissn><abstract>Type II porous liquids are demonstrated to be promise porous materials. However, the category of porous hosts is very limited. Here, a porous host metal–organic polyhedra (MOP‐18) is reported to construct type II porous liquids. MOP‐18 is dissolved into 15‐crown‐5 as an individual cage (5 nm). Both the molecular dynamics simulations and experimental gravimetric CO2 solubility test indicate that the inner cavity of MOP‐18 in porous liquids is unoccupied by 15‐crown‐5 and is accessible to CO2. Thus, the prepared porous liquids show enhanced gas solubility. Furthermore, the prepared porous liquid is encapsulated into graphene oxide (GO) nanoslits to form a GO‐supported porous liquid membrane (GO‐SPLM). Owing to the empty cavity of MOP‐18 unit cages in porous liquids that reduces the gas diffusion barrier, GO‐SPLM significantly enhances the permeability of gas.
A type II porous liquid is constructed by using MOP‐18 and 15‐crown‐5 as the porous host and bulky solvent, respectively. The existence of permanent porosity in porous liquid is confirmed by both the molecular dynamics simulations and experimental date. The unoccupied cavity in the porous liquid can be used for gas storage and facilitating the gas transportation.</abstract><cop>Germany</cop><pub>Wiley Subscription Services, Inc</pub><pmid>32083785</pmid><doi>10.1002/smll.201907016</doi><tpages>6</tpages><orcidid>https://orcid.org/0000-0002-5355-4854</orcidid></addata></record> |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Carbon dioxide Diffusion barriers Gas solubility Gas transport gas transportation Gaseous diffusion Graphene Gravimetry liquid membrane Liquid membranes Liquids metal–organic polyhedra Molecular dynamics MOP‐18 Nanotechnology Polyhedra porous liquid Porous materials type II porous liquids |
| title | Facilitate Gas Transport through Metal‐Organic Polyhedra Constructed Porous Liquid Membrane |
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