Chiral Aluminum Complex Controls Enantioselective Nickel‐Catalyzed Synthesis of Indenes: C−CN Bond Activation

A chiral aluminum complex controlled, enantioselective nickel‐catalyzed domino reaction of aryl nitriles and alkynes proceeding by C−CN bond activation was developed. The reaction provides various indenes, bearing chiral all‐carbon quaternary centers, under mild reaction conditions in yields of 32 t...

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Veröffentlicht in:	Angewandte Chemie International Edition 2020-05, Vol.59 (19), p.7439-7443
Hauptverfasser:	Zhang, Tao, Luan, Yu‐Xin, Zheng, Su‐Juan, Peng, Qian, Ye, Mengchun
Format:	Artikel
Sprache:	eng
Schlagworte:	Activation Alkynes Aluminum Aromatic compounds Cascade chemical reactions Chemical synthesis Cyanides cyclization Enantiomers Nickel Nitriles Reaction mechanisms synthetic methods
Online-Zugang:	Volltext
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