Thiol‐Ene Cationic and Radical Reactions: Cyclization, Step‐Growth, and Concurrent Polymerizations for Thioacetal and Thioether Units

Thiol‐ene cationic and radical reactions were conducted for 1:1 addition between a thiol and vinyl ether, and also for cyclization and step‐growth polymerization between a dithiol and divinyl ether. p‐Toluenesulfonic acid (PTSA) induced a cationic thiol‐ene reaction to generate a thioacetal in high...

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Veröffentlicht in:	Angewandte Chemie International Edition 2020-04, Vol.59 (17), p.6832-6838
Hauptverfasser:	Uchiyama, Mineto, Osumi, Masahiro, Satoh, Kotaro, Kamigaito, Masami
Format:	Artikel
Sprache:	eng
Schlagworte:	Azobisisobutyronitrile Cations copolymers cyclization Dilution Irradiation Polymerization Polymers radicals synthetic methods Ultraviolet radiation
Online-Zugang:	Volltext
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