Isotopically Directed Symmetry Breaking and Enantioenrichment in Attrition-Enhanced Deracemization

The evolution of homochirality via attrition-enhanced deracemization (AED) of enantiomorphic solids is carried out using molecules that differ only in the isotopic composition of a phenyl group positioned remote from the chiral center. Enantioenrichment consistently favors the enantiomorph containin...

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Veröffentlicht in:	Journal of the American Chemical Society 2020-02, Vol.142 (8), p.3873-3879
Hauptverfasser:	Murray, James I, Sanders, Jacob N, Richardson, Paul F, Houk, K. N, Blackmond, Donna G
Format:	Artikel
Sprache:	eng
Schlagworte:	Isotopes - chemistry Molecular Structure Solubility Stereoisomerism
Online-Zugang:	Volltext
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