Planarity does not always mean higher aromaticity – Intriguing metalloaromaticity of three Al13+ isomers

A pair of Al13+ clusters, one perfectly planar (CI) and another quasi-planar structure (CII) have been reported recently by our group [Guin et al. Journal of Molecular Modeling, 2018, 24, 344]. Both these clusters are rare examples of metal-aromatic systems having unique aromatic character. In these...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Journal of molecular graphics & modelling 2020-06, Vol.97, p.107544-107544, Article 107544
Hauptverfasser:	Guin, Surajit, Ghosh, Sourav Ranjan, Jana, Atish Dipankar
Format:	Artikel
Sprache:	eng
Schlagworte:	AIM and AdNDP analysis Aromaticity and antiaromaticity NICS, ELF, LOL analysis Planar/quasi-planar aluminium cluster Transition state
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!