Unusual luminescence behaviour of terbium phosphate glasses
While preparing a terbium-containing phosphate glass, an intense emission of green light was observed when the melt was poured into a metal mould. This emission was easily visible to the naked eye and was only observed on quenching of the melts. To our knowledge this phenomenon, termed ‘cooling-indu...
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| Veröffentlicht in: | Nature (London) 1982-01, Vol.295 (5851), p.680-682 |
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| container_issue | 5851 |
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| container_title | Nature (London) |
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| creator | Cronin, David J. Blackburn, Douglas H. Haller, Wolfgang K. |
| description | While preparing a terbium-containing phosphate glass, an intense emission of green light was observed when the melt was poured into a metal mould. This emission was easily visible to the naked eye and was only observed on quenching of the melts. To our knowledge this phenomenon, termed ‘cooling-induced luminescence (CIL)’, has not previously been reported. Experimental evidence suggests that the CIL may be related to a thermally induced shift in the oxidation-reduction balance in the melt. A similar phenomenon was also observed with europium phosphate melts. |
| doi_str_mv | 10.1038/295680b0 |
| format | Article |
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This emission was easily visible to the naked eye and was only observed on quenching of the melts. To our knowledge this phenomenon, termed ‘cooling-induced luminescence (CIL)’, has not previously been reported. Experimental evidence suggests that the CIL may be related to a thermally induced shift in the oxidation-reduction balance in the melt. 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This emission was easily visible to the naked eye and was only observed on quenching of the melts. To our knowledge this phenomenon, termed ‘cooling-induced luminescence (CIL)’, has not previously been reported. Experimental evidence suggests that the CIL may be related to a thermally induced shift in the oxidation-reduction balance in the melt. 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| subjects | Humanities and Social Sciences letter multidisciplinary Science Science (multidisciplinary) |
| title | Unusual luminescence behaviour of terbium phosphate glasses |
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