Infrared Spectrum of CO on a Platinum Electrode in Acidic Solution

Polarization-modulated infrared reflection absorption spectroscopy has been used to measure the spectrum of adsorbed CO on a Pt electrode in both 1 M H sub 2 SO sub 4 and 1 M HClO sub 4 saturated with CO gas. This is the first direct measurement of the infrared band of adsorbed CO on an active elect...

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Veröffentlicht in:Journal of physical chemistry (1952) 1982-01, Vol.86 (16), p.3066-3068
Hauptverfasser: Russell, J W, Overend, J, Scanlon, K, Severson, M, Bewick, A
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container_end_page 3068
container_issue 16
container_start_page 3066
container_title Journal of physical chemistry (1952)
container_volume 86
creator Russell, J W
Overend, J
Scanlon, K
Severson, M
Bewick, A
description Polarization-modulated infrared reflection absorption spectroscopy has been used to measure the spectrum of adsorbed CO on a Pt electrode in both 1 M H sub 2 SO sub 4 and 1 M HClO sub 4 saturated with CO gas. This is the first direct measurement of the infrared band of adsorbed CO on an active electrode and definitively establishes the dependence of the band wave number on electrode potential as the primary source of the unusual bisignate band previously observed with electrode-modulated infrared spectroscopy.--AA
doi_str_mv 10.1021/j100213a005
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title Infrared Spectrum of CO on a Platinum Electrode in Acidic Solution
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