Dual Naked-Eye Optical Sensor Based on Imidazolium Cation and Napthalamide for Specific Detection of Fluoride

A novel naked eye fluorescence sensor ( ANI ) based on naphthalimide and imidazolium moieties for fluoride detection has been designed and synthesized by multiple step synthesis. The fluorescence response of ANI sensor was significantly quenched in the presence of fluoride ion upon the interaction b...

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Veröffentlicht in:Journal of fluorescence 2020-03, Vol.30 (2), p.259-267
Hauptverfasser: Kongwutthivech, Jaturong, Tuntulani, Thawatchai, Promarak, Vinich, Tomapatanaget, Boosayarat
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container_end_page 267
container_issue 2
container_start_page 259
container_title Journal of fluorescence
container_volume 30
creator Kongwutthivech, Jaturong
Tuntulani, Thawatchai
Promarak, Vinich
Tomapatanaget, Boosayarat
description A novel naked eye fluorescence sensor ( ANI ) based on naphthalimide and imidazolium moieties for fluoride detection has been designed and synthesized by multiple step synthesis. The fluorescence response of ANI sensor was significantly quenched in the presence of fluoride ion upon the interaction between an acidic amide proton and acidic C2 proton (-C(2) H -) of imidazolium compound. The binding behavior of ANI and F − ion was extensively explored by using NMR titration. Comparison of binding ability of ANI and AN sensors addressed the dominant electrostatic and hydrogen bonding interaction with F − ion. Consequently, ANI sensor highlights a strong binding with F − ions with a high selectivity over AN . Interestingly, ANI demonstrated a naked-eye response with colorimetric and fluorometric assay.
doi_str_mv 10.1007/s10895-020-02494-2
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subjects Analytical Chemistry
Binding
Biochemistry
Biological and Medical Physics
Biomedical and Life Sciences
Biomedicine
Biophysics
Biotechnology
Bonding strength
Chemical bonds
Colorimetry
Fluorescence
Fluorides
Hydrogen bonding
NMR
Nuclear magnetic resonance
Optical measuring instruments
Original Article
Protons
Selectivity
Sensors
Titration
title Dual Naked-Eye Optical Sensor Based on Imidazolium Cation and Napthalamide for Specific Detection of Fluoride
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