Dual Naked-Eye Optical Sensor Based on Imidazolium Cation and Napthalamide for Specific Detection of Fluoride
A novel naked eye fluorescence sensor ( ANI ) based on naphthalimide and imidazolium moieties for fluoride detection has been designed and synthesized by multiple step synthesis. The fluorescence response of ANI sensor was significantly quenched in the presence of fluoride ion upon the interaction b...
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Veröffentlicht in: | Journal of fluorescence 2020-03, Vol.30 (2), p.259-267 |
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container_title | Journal of fluorescence |
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creator | Kongwutthivech, Jaturong Tuntulani, Thawatchai Promarak, Vinich Tomapatanaget, Boosayarat |
description | A novel naked eye fluorescence sensor
(
ANI
)
based on naphthalimide and imidazolium moieties for fluoride detection has been designed and synthesized by multiple step synthesis. The fluorescence response of
ANI
sensor was significantly quenched in the presence of fluoride ion upon the interaction between an acidic amide proton and acidic C2 proton (-C(2)
H
-) of imidazolium compound. The binding behavior of
ANI
and F
−
ion was extensively explored by using NMR titration. Comparison of binding ability of
ANI
and
AN
sensors addressed the dominant electrostatic and hydrogen bonding interaction with F
−
ion. Consequently,
ANI
sensor highlights a strong binding with F
−
ions with a high selectivity over
AN
. Interestingly,
ANI
demonstrated a naked-eye response with colorimetric and fluorometric assay. |
doi_str_mv | 10.1007/s10895-020-02494-2 |
format | Article |
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(
ANI
)
based on naphthalimide and imidazolium moieties for fluoride detection has been designed and synthesized by multiple step synthesis. The fluorescence response of
ANI
sensor was significantly quenched in the presence of fluoride ion upon the interaction between an acidic amide proton and acidic C2 proton (-C(2)
H
-) of imidazolium compound. The binding behavior of
ANI
and F
−
ion was extensively explored by using NMR titration. Comparison of binding ability of
ANI
and
AN
sensors addressed the dominant electrostatic and hydrogen bonding interaction with F
−
ion. Consequently,
ANI
sensor highlights a strong binding with F
−
ions with a high selectivity over
AN
. Interestingly,
ANI
demonstrated a naked-eye response with colorimetric and fluorometric assay.</description><identifier>ISSN: 1053-0509</identifier><identifier>EISSN: 1573-4994</identifier><identifier>DOI: 10.1007/s10895-020-02494-2</identifier><identifier>PMID: 31989418</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Analytical Chemistry ; Binding ; Biochemistry ; Biological and Medical Physics ; Biomedical and Life Sciences ; Biomedicine ; Biophysics ; Biotechnology ; Bonding strength ; Chemical bonds ; Colorimetry ; Fluorescence ; Fluorides ; Hydrogen bonding ; NMR ; Nuclear magnetic resonance ; Optical measuring instruments ; Original Article ; Protons ; Selectivity ; Sensors ; Titration</subject><ispartof>Journal of fluorescence, 2020-03, Vol.30 (2), p.259-267</ispartof><rights>Springer Science+Business Media, LLC, part of Springer Nature 2020</rights><rights>2020© Springer Science+Business Media, LLC, part of Springer Nature 2020</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c375t-ffb82498e04feb98abe833097ad560cfd1c543434b6fcb571e89f2431316e0293</citedby><cites>FETCH-LOGICAL-c375t-ffb82498e04feb98abe833097ad560cfd1c543434b6fcb571e89f2431316e0293</cites><orcidid>0000-0002-6378-0919</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10895-020-02494-2$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10895-020-02494-2$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27923,27924,41487,42556,51318</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/31989418$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Kongwutthivech, Jaturong</creatorcontrib><creatorcontrib>Tuntulani, Thawatchai</creatorcontrib><creatorcontrib>Promarak, Vinich</creatorcontrib><creatorcontrib>Tomapatanaget, Boosayarat</creatorcontrib><title>Dual Naked-Eye Optical Sensor Based on Imidazolium Cation and Napthalamide for Specific Detection of Fluoride</title><title>Journal of fluorescence</title><addtitle>J Fluoresc</addtitle><addtitle>J Fluoresc</addtitle><description>A novel naked eye fluorescence sensor
(
ANI
)
based on naphthalimide and imidazolium moieties for fluoride detection has been designed and synthesized by multiple step synthesis. The fluorescence response of
ANI
sensor was significantly quenched in the presence of fluoride ion upon the interaction between an acidic amide proton and acidic C2 proton (-C(2)
H
-) of imidazolium compound. The binding behavior of
ANI
and F
−
ion was extensively explored by using NMR titration. Comparison of binding ability of
ANI
and
AN
sensors addressed the dominant electrostatic and hydrogen bonding interaction with F
−
ion. Consequently,
ANI
sensor highlights a strong binding with F
−
ions with a high selectivity over
AN
. Interestingly,
ANI
demonstrated a naked-eye response with colorimetric and fluorometric assay.</description><subject>Analytical Chemistry</subject><subject>Binding</subject><subject>Biochemistry</subject><subject>Biological and Medical Physics</subject><subject>Biomedical and Life Sciences</subject><subject>Biomedicine</subject><subject>Biophysics</subject><subject>Biotechnology</subject><subject>Bonding strength</subject><subject>Chemical bonds</subject><subject>Colorimetry</subject><subject>Fluorescence</subject><subject>Fluorides</subject><subject>Hydrogen bonding</subject><subject>NMR</subject><subject>Nuclear magnetic resonance</subject><subject>Optical measuring instruments</subject><subject>Original Article</subject><subject>Protons</subject><subject>Selectivity</subject><subject>Sensors</subject><subject>Titration</subject><issn>1053-0509</issn><issn>1573-4994</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNp9kc1O3TAQha2qVYHbvgALZKmbbgLj2L6xl-3lV0JlQbuOHGdMQ5M4tZMFPH0HLgWJBbIsj2a-M7bnMLYv4FAAVEdZgLG6gBJoK6uK8h3bFbqShbJWvacYtCxAg91heznfAoA1ynxkO1JYY5Uwu2w4XlzPf7g_2BYnd8ivprnzlLnGMcfEv7uMLY8jvxi61t3HvlsGvnFzRyk3tiSc5t-ud1RFHkhwPaHvQuf5Mc7oH7kY-Gm_xETIJ_YhuD7j56dzxX6dnvzcnBeXV2cXm2-XhZeVnosQGkMfMggqYGONa9BICbZyrV6DD63wWklazTr4RlcCjQ2lkkKKNUJp5Yp93fadUvy7YJ7rocse-96NGJdcl1JVuiyV0YR-eYXexiWN9DqiaFprMMYQVW4pn2LOCUM9pW5w6a4WUD-YUW_NqMmM-tEMUq_YwVPrpRmwfZb8nz4BcgtkKo03mF7ufqPtP5LAk80</recordid><startdate>20200301</startdate><enddate>20200301</enddate><creator>Kongwutthivech, Jaturong</creator><creator>Tuntulani, Thawatchai</creator><creator>Promarak, Vinich</creator><creator>Tomapatanaget, Boosayarat</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0002-6378-0919</orcidid></search><sort><creationdate>20200301</creationdate><title>Dual Naked-Eye Optical Sensor Based on Imidazolium Cation and Napthalamide for Specific Detection of Fluoride</title><author>Kongwutthivech, Jaturong ; Tuntulani, Thawatchai ; Promarak, Vinich ; Tomapatanaget, Boosayarat</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c375t-ffb82498e04feb98abe833097ad560cfd1c543434b6fcb571e89f2431316e0293</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Analytical Chemistry</topic><topic>Binding</topic><topic>Biochemistry</topic><topic>Biological and Medical Physics</topic><topic>Biomedical and Life Sciences</topic><topic>Biomedicine</topic><topic>Biophysics</topic><topic>Biotechnology</topic><topic>Bonding strength</topic><topic>Chemical bonds</topic><topic>Colorimetry</topic><topic>Fluorescence</topic><topic>Fluorides</topic><topic>Hydrogen bonding</topic><topic>NMR</topic><topic>Nuclear magnetic resonance</topic><topic>Optical measuring instruments</topic><topic>Original Article</topic><topic>Protons</topic><topic>Selectivity</topic><topic>Sensors</topic><topic>Titration</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kongwutthivech, Jaturong</creatorcontrib><creatorcontrib>Tuntulani, Thawatchai</creatorcontrib><creatorcontrib>Promarak, Vinich</creatorcontrib><creatorcontrib>Tomapatanaget, Boosayarat</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Journal of fluorescence</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kongwutthivech, Jaturong</au><au>Tuntulani, Thawatchai</au><au>Promarak, Vinich</au><au>Tomapatanaget, Boosayarat</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Dual Naked-Eye Optical Sensor Based on Imidazolium Cation and Napthalamide for Specific Detection of Fluoride</atitle><jtitle>Journal of fluorescence</jtitle><stitle>J Fluoresc</stitle><addtitle>J Fluoresc</addtitle><date>2020-03-01</date><risdate>2020</risdate><volume>30</volume><issue>2</issue><spage>259</spage><epage>267</epage><pages>259-267</pages><issn>1053-0509</issn><eissn>1573-4994</eissn><abstract>A novel naked eye fluorescence sensor
(
ANI
)
based on naphthalimide and imidazolium moieties for fluoride detection has been designed and synthesized by multiple step synthesis. The fluorescence response of
ANI
sensor was significantly quenched in the presence of fluoride ion upon the interaction between an acidic amide proton and acidic C2 proton (-C(2)
H
-) of imidazolium compound. The binding behavior of
ANI
and F
−
ion was extensively explored by using NMR titration. Comparison of binding ability of
ANI
and
AN
sensors addressed the dominant electrostatic and hydrogen bonding interaction with F
−
ion. Consequently,
ANI
sensor highlights a strong binding with F
−
ions with a high selectivity over
AN
. Interestingly,
ANI
demonstrated a naked-eye response with colorimetric and fluorometric assay.</abstract><cop>New York</cop><pub>Springer US</pub><pmid>31989418</pmid><doi>10.1007/s10895-020-02494-2</doi><tpages>9</tpages><orcidid>https://orcid.org/0000-0002-6378-0919</orcidid></addata></record> |
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language | eng |
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source | SpringerLink Journals - AutoHoldings |
subjects | Analytical Chemistry Binding Biochemistry Biological and Medical Physics Biomedical and Life Sciences Biomedicine Biophysics Biotechnology Bonding strength Chemical bonds Colorimetry Fluorescence Fluorides Hydrogen bonding NMR Nuclear magnetic resonance Optical measuring instruments Original Article Protons Selectivity Sensors Titration |
title | Dual Naked-Eye Optical Sensor Based on Imidazolium Cation and Napthalamide for Specific Detection of Fluoride |
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