Modular Synthesis of Carbon-Substituted Furoxans via Radical Addition Pathway. Useful Tool for Transformation of Aliphatic Carboxylic Acids Based on “Build-and-Scrap” Strategy
Utilizing radical chemistry, a new general C–C bond formation on the furoxan ring was developed. By taking advantage of the lability of furoxans, a wide variety of transformation of the synthesized furoxans have been demonstrated. Thus, this developed methodology enabled not only the modular synthes...
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Veröffentlicht in: | Organic letters 2020-02, Vol.22 (3), p.1182-1187 |
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container_title | Organic letters |
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creator | Matsubara, Ryosuke Kim, Hojin Sakaguchi, Takaya Xie, Weibin Zhao, Xufeng Nagoshi, Yuto Wang, Chaoyu Tateiwa, Masahiro Ando, Akihiro Hayashi, Masahiko Yamanaka, Masahiro Tsuneda, Takao |
description | Utilizing radical chemistry, a new general C–C bond formation on the furoxan ring was developed. By taking advantage of the lability of furoxans, a wide variety of transformation of the synthesized furoxans have been demonstrated. Thus, this developed methodology enabled not only the modular synthesis of furoxans but also short-step transformations of carboxylic acids to a broad range of functional groups. |
doi_str_mv | 10.1021/acs.orglett.0c00062 |
format | Article |
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title | Modular Synthesis of Carbon-Substituted Furoxans via Radical Addition Pathway. Useful Tool for Transformation of Aliphatic Carboxylic Acids Based on “Build-and-Scrap” Strategy |
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